FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321894106> ?p ?o ?g. }

• W2321894106 abstract "We propose a generalized one-dimensional kinetic equation for multidimensional reversible electron transfer (ET) reaction with a nonequilibrium situation as the initial condition. The rate constant for the forward reversible ET reaction obtained here consists of the rate for the corresponding irreversible ET reaction, and an extra term due to reversibility of the ET process which includes the rates of diffusion dynamics in the reactant and product wells. In order to understand the effect of reversibility, we consider back ET reaction in a system consisting of an electron donor-acceptor pair in a solvent modeled through low frequency solvent collective coordinates (multidimensional) characterized by the orientational polarization and slowly relaxing one-dimensional vibrational mode. We propose here a new generalized polarization energy functional corresponding to the extension of the continuum version for the same, which has opened up the possibility of inclusion of molecular nature of the solvent into the solvent reorganization energy. We then derive an exact expression for the ET rate for this model system. The numerical results calculated by using the proposed one-dimensional approach are shown to be in good agreement with the available experimental results. Non-Marcus free energy gap dependence of the rates observed here for the reversible and irreversible ET reactions are very close to each other in the barrierless region, while for other situations, the rate for the former process is found to be less than the latter. The extra term, which makes the difference between the rate constants for irreversible and reversible ET reactions, is found to be contributed by the diffusion dynamics from both reactant and product wells but the dominating contribution is provided mainly by the product well." @default.
• W2321894106 created "2016-06-24" @default.
• W2321894106 creator A5043486747 @default.
• W2321894106 creator A5049423759 @default.
• W2321894106 creator A5049587476 @default.
• W2321894106 creator A5091301398 @default.
• W2321894106 date "2012-02-07" @default.
• W2321894106 modified "2023-09-23" @default.
• W2321894106 title "Electron transfer reactions in condensed phase: Effect of reversibility" @default.
• W2321894106 cites W1966489140 @default.
• W2321894106 cites W1966529531 @default.
• W2321894106 cites W1967979368 @default.
• W2321894106 cites W1972850602 @default.
• W2321894106 cites W1973029228 @default.
• W2321894106 cites W1976660933 @default.
• W2321894106 cites W1979129222 @default.
• W2321894106 cites W1980996086 @default.
• W2321894106 cites W1981554467 @default.
• W2321894106 cites W1983663688 @default.
• W2321894106 cites W1985263361 @default.
• W2321894106 cites W1990087252 @default.
• W2321894106 cites W1998533858 @default.
• W2321894106 cites W2016090732 @default.
• W2321894106 cites W2017087759 @default.
• W2321894106 cites W2018446619 @default.
• W2321894106 cites W2018874035 @default.
• W2321894106 cites W2020003535 @default.
• W2321894106 cites W2028168007 @default.
• W2321894106 cites W2036610165 @default.
• W2321894106 cites W2036668414 @default.
• W2321894106 cites W2037300247 @default.
• W2321894106 cites W2045263347 @default.
• W2321894106 cites W2054836061 @default.
• W2321894106 cites W2055442639 @default.
• W2321894106 cites W2064895134 @default.
• W2321894106 cites W2066725792 @default.
• W2321894106 cites W2067874694 @default.
• W2321894106 cites W2068326432 @default.
• W2321894106 cites W2070970172 @default.
• W2321894106 cites W2074632248 @default.
• W2321894106 cites W2074768610 @default.
• W2321894106 cites W2076004384 @default.
• W2321894106 cites W2076622858 @default.
• W2321894106 cites W2079590432 @default.
• W2321894106 cites W2083088477 @default.
• W2321894106 cites W2084333107 @default.
• W2321894106 cites W2091237955 @default.
• W2321894106 cites W2095216354 @default.
• W2321894106 cites W2104166397 @default.
• W2321894106 cites W2127737840 @default.
• W2321894106 cites W1988443289 @default.
• W2321894106 doi "https://doi.org/10.1103/physreve.85.026105" @default.
• W2321894106 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22463277" @default.
• W2321894106 hasPublicationYear "2012" @default.
• W2321894106 type Work @default.
• W2321894106 sameAs 2321894106 @default.
• W2321894106 citedByCount "8" @default.
• W2321894106 countsByYear W23218941062015 @default.
• W2321894106 countsByYear W23218941062017 @default.
• W2321894106 countsByYear W23218941062019 @default.
• W2321894106 countsByYear W23218941062020 @default.
• W2321894106 countsByYear W23218941062022 @default.
• W2321894106 crossrefType "journal-article" @default.
• W2321894106 hasAuthorship W2321894106A5043486747 @default.
• W2321894106 hasAuthorship W2321894106A5049423759 @default.
• W2321894106 hasAuthorship W2321894106A5049587476 @default.
• W2321894106 hasAuthorship W2321894106A5091301398 @default.
• W2321894106 hasConcept C121332964 @default.
• W2321894106 hasConcept C121864883 @default.
• W2321894106 hasConcept C123669783 @default.
• W2321894106 hasConcept C132439834 @default.
• W2321894106 hasConcept C135889238 @default.
• W2321894106 hasConcept C147789679 @default.
• W2321894106 hasConcept C148898269 @default.
• W2321894106 hasConcept C159467904 @default.
• W2321894106 hasConcept C161790260 @default.
• W2321894106 hasConcept C175113610 @default.
• W2321894106 hasConcept C178790620 @default.
• W2321894106 hasConcept C185592680 @default.
• W2321894106 hasConcept C2780471494 @default.
• W2321894106 hasConcept C55493867 @default.
• W2321894106 hasConcept C62520636 @default.
• W2321894106 hasConcept C74859849 @default.
• W2321894106 hasConcept C89169741 @default.
• W2321894106 hasConcept C93391505 @default.
• W2321894106 hasConcept C97355855 @default.
• W2321894106 hasConceptScore W2321894106C121332964 @default.
• W2321894106 hasConceptScore W2321894106C121864883 @default.
• W2321894106 hasConceptScore W2321894106C123669783 @default.
• W2321894106 hasConceptScore W2321894106C132439834 @default.
• W2321894106 hasConceptScore W2321894106C135889238 @default.
• W2321894106 hasConceptScore W2321894106C147789679 @default.
• W2321894106 hasConceptScore W2321894106C148898269 @default.
• W2321894106 hasConceptScore W2321894106C159467904 @default.
• W2321894106 hasConceptScore W2321894106C161790260 @default.
• W2321894106 hasConceptScore W2321894106C175113610 @default.
• W2321894106 hasConceptScore W2321894106C178790620 @default.
• W2321894106 hasConceptScore W2321894106C185592680 @default.
• W2321894106 hasConceptScore W2321894106C2780471494 @default.
• W2321894106 hasConceptScore W2321894106C55493867 @default.

• next