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- W2321898624 abstract "Ordered, hierarchical (triple-scale), superhydrophobic, oleophobic, superoleophobic, and amphiphilic surfaces on poly(methyl methacrylate) PMMA polymer substrates are fabricated using polystyrene (PS) microparticle colloidal lithography, followed by oxygen plasma etching-nanotexturing (for amphiphilic surfaces) and optional subsequent fluorocarbon plasma deposition (for amphiphobic surfaces). The PS colloidal microparticles were assembled by spin-coating. After etching/nanotexturing, the PMMA plates are amphiphilic and exhibit hierarchical (triple-scale) roughness with microscale ordered columns, and dual-scale (hundred nano/ten nano meter) nanoscale texture on the particles (top of the column) and on the etched PMMA surface. The spacing, diameter, height, and reentrant profile of the microcolumns are controlled with the etching process. Following the design requirements for superamphiphobic surfaces, we demonstrate enhancement of both hydrophobicity and oleophobicity as a result of hierarchical (triple-scale) and re-entrant topography. After fluorocarbon film deposition, we demonstrate superhydrophobic surfaces (contact angle for water 168°, compared to 110° for a flat surface), as well as superoleophobic surfaces (153° for diiodomethane, compared to 80° for a flat surface)." @default.
- W2321898624 created "2016-06-24" @default.
- W2321898624 creator A5001152021 @default.
- W2321898624 creator A5078451590 @default.
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- W2321898624 date "2011-02-25" @default.
- W2321898624 modified "2023-10-01" @default.
- W2321898624 title "From Superamphiphobic to Amphiphilic Polymeric Surfaces with Ordered Hierarchical Roughness Fabricated with Colloidal Lithography and Plasma Nanotexturing" @default.
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- W2321898624 doi "https://doi.org/10.1021/la104481p" @default.
- W2321898624 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21351799" @default.
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