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- W2321918559 abstract "The solvent extraction equilibrium of zinc with 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHPNA) in an alkane diluent, Shellsol D70, was studied at a constant ionic strength of 1 mol/L from nitrate solutions considering the correction of the extractant nonideality in the organic phase by Alstad’s method. On the basis of the slope analysis of the obtained data, a molar ratio of 1:2 for the zinc to the EHPNA dimer in the extracted complex was indicated. Apparent extraction equilibrium constants obtained at each temperature from 283 to 323 K showed the endothermic nature of the extraction reaction and gave the apparent standard enthalpy and entropy changes. These two constants enable the calculation of the zinc distribution ratio at each temperature which correlates the experimental data with good accuracy." @default.
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- W2321918559 date "2012-12-04" @default.
- W2321918559 modified "2023-10-18" @default.
- W2321918559 title "Solvent Extraction Equilibrium of Zinc from Nitrate Solutions with 2-Ethylhexylphosphonic Acid Mono-2-ethylhexyl Ester" @default.
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- W2321918559 doi "https://doi.org/10.1021/ie301589s" @default.
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