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- W2321929231 abstract "This study presents the synthesis of microporous polystyrene particles and the potential use of these materials in CO(2) capture for biogas purification. Highly cross-linked polystyrene particles are synthesized by the emulsion copolymerization of styrene (St) and divinylbenzene (DVB) in water. The cross-link density of the polymer is varied by altering the St/DVB molar ratio. The size and the morphology of the particles are characterized by scanning and transmission electron microscopy. Following supercritical point drying with carbon dioxide or lyophilization from benzene, the polystyrene nanoparticles exhibit a significant surface area and permanent microporosity. The dried particles comprising 35 mol % St and 65 mol % DVB possess the largest surface area, ∼205 m(2)/g measured by Brunauer-Emmett-Teller and ∼185 m(2)/g measured by the Dubinin-Radushkevich method, and a total pore volume of 1.10 cm(3)/g. Low pressure measurements suggest that the microporous polystyrene particles exhibit a good separation performance of CO(2) over CH(4), with separation factors in the range of ∼7-13 (268 K, CO(2)/CH(4) = 5/95 gas mixture), which renders them attractive candidates for use in gas separation processes." @default.
- W2321929231 created "2016-06-24" @default.
- W2321929231 creator A5024889380 @default.
- W2321929231 creator A5027499590 @default.
- W2321929231 creator A5089743539 @default.
- W2321929231 date "2012-01-23" @default.
- W2321929231 modified "2023-09-25" @default.
- W2321929231 title "Microporous Polystyrene Particles for Selective Carbon Dioxide Capture" @default.
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- W2321929231 doi "https://doi.org/10.1021/la204991n" @default.
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