FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321931021> ?p ?o ?g. }

• W2321931021 endingPage "1971" @default.
• W2321931021 startingPage "1964" @default.
• W2321931021 abstract "Reductive elimination from U(CH2Ph)4 (1-Ph) mediated by 4,6-di-tert-butyl-2-[(2,6-diisopropylphenyl)imino]quinone (dippiq) was observed, resulting in the formation of (dippap)2U(CH2Ph)2(THF)2 (2) (dippap = 4,6-di-tert-butyl-2-[(2,6-diisopropylphenyl)amido]phenolate) and bibenzyl. The crossover experiment with U(CD2C6D5)4 showed formation of bibenzyl-d7, indicating that reductive elimination occurs in a stepwise fashion via benzyl radical extrusion, presumably through an iminosemiquinone tris(benzyl) intermediate, (dippisq)U(CH2Ph)3. Synthesis of this intermediate was attempted by addition of the iminoquinone ligand to UI3(THF)4 to form (dippisq)UI3 (3), followed by alkylation with 3 equiv of benzylpotassium. However, this only resulted in the isolation of 2. Reduction of 3 with KC8 afforded the amidophenolate diiodide species (dippap)UI2(THF)2 (4), maintaining the tetravalent oxidation state of the uranium and reducing the ligand. Attempts at the formation of 2 via addition of 2 equiv of benzylpotassium to 4 resulted in decomposition. The uranium mono(alkyl) (dippap)UI(CH2Ph)(THF)2 (5) was observed upon addition of 1 equiv of benzylpotassium to 4. All products have been characterized by 1H NMR and electronic absorption spectroscopy. X-ray crystallography was employed to ascertain ligand reduction in 2, 3, and 5." @default.
• W2321931021 created "2016-06-24" @default.
• W2321931021 creator A5016331643 @default.
• W2321931021 creator A5022420870 @default.
• W2321931021 creator A5025292729 @default.
• W2321931021 creator A5036183082 @default.
• W2321931021 creator A5037627801 @default.
• W2321931021 creator A5057330382 @default.
• W2321931021 date "2014-04-07" @default.
• W2321931021 modified "2023-10-02" @default.
• W2321931021 title "Radical Reductive Elimination from Tetrabenzyluranium Mediated by an Iminoquinone Ligand" @default.
• W2321931021 cites W1968499321 @default.
• W2321931021 cites W1968645459 @default.
• W2321931021 cites W1968849593 @default.
• W2321931021 cites W1971038878 @default.
• W2321931021 cites W1973415300 @default.
• W2321931021 cites W1974098430 @default.
• W2321931021 cites W1975964562 @default.
• W2321931021 cites W1976263143 @default.
• W2321931021 cites W1976436568 @default.
• W2321931021 cites W1986268321 @default.
• W2321931021 cites W1990235319 @default.
• W2321931021 cites W1998731725 @default.
• W2321931021 cites W2000466466 @default.
• W2321931021 cites W2012209451 @default.
• W2321931021 cites W2014702517 @default.
• W2321931021 cites W2015697377 @default.
• W2321931021 cites W2016425542 @default.
• W2321931021 cites W2018503984 @default.
• W2321931021 cites W2019354728 @default.
• W2321931021 cites W2022330705 @default.
• W2321931021 cites W2028494991 @default.
• W2321931021 cites W2034574511 @default.
• W2321931021 cites W2046522513 @default.
• W2321931021 cites W2052235507 @default.
• W2321931021 cites W2056980657 @default.
• W2321931021 cites W2065133910 @default.
• W2321931021 cites W2065205106 @default.
• W2321931021 cites W2069051326 @default.
• W2321931021 cites W2070966847 @default.
• W2321931021 cites W2072913637 @default.
• W2321931021 cites W2077247493 @default.
• W2321931021 cites W2080914325 @default.
• W2321931021 cites W2084944949 @default.
• W2321931021 cites W2085055453 @default.
• W2321931021 cites W2085060460 @default.
• W2321931021 cites W2089255597 @default.
• W2321931021 cites W2093247010 @default.
• W2321931021 cites W2108271691 @default.
• W2321931021 cites W2125091061 @default.
• W2321931021 cites W2131350133 @default.
• W2321931021 cites W2142311740 @default.
• W2321931021 cites W2283220043 @default.
• W2321931021 cites W2312319623 @default.
• W2321931021 cites W2312674689 @default.
• W2321931021 cites W2313763470 @default.
• W2321931021 cites W2316057627 @default.
• W2321931021 cites W2328860291 @default.
• W2321931021 cites W2335160923 @default.
• W2321931021 cites W2413091549 @default.
• W2321931021 cites W2493803916 @default.
• W2321931021 doi "https://doi.org/10.1021/om4012104" @default.
• W2321931021 hasPublicationYear "2014" @default.
• W2321931021 type Work @default.
• W2321931021 sameAs 2321931021 @default.
• W2321931021 citedByCount "33" @default.
• W2321931021 countsByYear W23219310212014 @default.
• W2321931021 countsByYear W23219310212015 @default.
• W2321931021 countsByYear W23219310212016 @default.
• W2321931021 countsByYear W23219310212017 @default.
• W2321931021 countsByYear W23219310212018 @default.
• W2321931021 countsByYear W23219310212019 @default.
• W2321931021 countsByYear W23219310212020 @default.
• W2321931021 countsByYear W23219310212021 @default.
• W2321931021 countsByYear W23219310212022 @default.
• W2321931021 countsByYear W23219310212023 @default.
• W2321931021 crossrefType "journal-article" @default.
• W2321931021 hasAuthorship W2321931021A5016331643 @default.
• W2321931021 hasAuthorship W2321931021A5022420870 @default.
• W2321931021 hasAuthorship W2321931021A5025292729 @default.
• W2321931021 hasAuthorship W2321931021A5036183082 @default.
• W2321931021 hasAuthorship W2321931021A5037627801 @default.
• W2321931021 hasAuthorship W2321931021A5057330382 @default.
• W2321931021 hasConcept C116569031 @default.
• W2321931021 hasConcept C124681953 @default.
• W2321931021 hasConcept C155647269 @default.
• W2321931021 hasConcept C161790260 @default.
• W2321931021 hasConcept C164361826 @default.
• W2321931021 hasConcept C170493617 @default.
• W2321931021 hasConcept C178790620 @default.
• W2321931021 hasConcept C185592680 @default.
• W2321931021 hasConcept C191897082 @default.
• W2321931021 hasConcept C192562407 @default.
• W2321931021 hasConcept C2778451082 @default.
• W2321931021 hasConcept C2778815869 @default.
• W2321931021 hasConcept C55493867 @default.
• W2321931021 hasConcept C555451288 @default.
• W2321931021 hasConcept C71240020 @default.

• next