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- W2321950257 abstract "The effect of the temperature on the surface layering of ionic liquids has been studied for two ionic liquids, trioctylmethylammonium bis(nonafluorobutanesulfonyl)amide([TOMA(+)][C(4)C(4)N(-)]) and trihexyltetradecylphosphonium bis(nonafluorobutanesulfonyl)amide ([THTDP(+)][C(4)C(4)N(-)]), using X-ray reflectivity measurements at 285, 300, and 315 K. Both [TOMA(+)][C(4)C(4)N(-)] and [THTDP(+)][C(4)C(4)N(-)] develop multilayers at the surface. The structure of the multilayers at the [TOMA(+)][C(4)C(4)N(-)] surface shows little temperature-dependent change, whereas that at the [THTDP(+)][C(4)C(4)N(-)] surface clearly becomes diffused with increasing temperature. The different temperature dependence seems to be related to the difference in the recently reported ultraslow dynamics of the interfacial structure of [TOMA(+)][C(4)C(4)N(-)] and [THTDP(+)][C(4)C(4)N(-)] at the ionic liquid|water interface." @default.
- W2321950257 created "2016-06-24" @default.
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- W2321950257 date "2011-05-19" @default.
- W2321950257 modified "2023-10-14" @default.
- W2321950257 title "Temperature Dependence of Multilayering at the Free Surface of Ionic Liquids Probed by X-ray Reflectivity Measurements" @default.
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- W2321950257 doi "https://doi.org/10.1021/la200252z" @default.
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