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• W2321983323 abstract "Using the Leibler–Ohta–Kawasaki (LOK) phase-field model of block copolymers (BCPs), we characterize how line-width roughness (LWR) in the chemoepitaxial template affects the BCP microdomain shape. Specifically, we derive formulas for the monomer density and the microdomain interface profile of periodic, lamellar BCP melts whose template lines widths oscillate with frequency k. The key idea behind our approach is to identify variations in the microdomain interface positions (relative to their averages) as corresponding to a local excess of one of the monomer types. For lamellar systems, our analysis (i) shows that the BCP morphology arises from the constraint that the total mass in a microdomain is fixed, independent of LWR, and (ii) determines a length scale λ over which template LWR affects the polymer melt." @default.
• W2321983323 created "2016-06-24" @default.
• W2321983323 creator A5033877939 @default.
• W2321983323 creator A5043003129 @default.
• W2321983323 date "2014-07-03" @default.
• W2321983323 modified "2023-09-26" @default.
• W2321983323 title "Response of Block Copolymer Thin-Film Morphology to Line-Width Roughness on a Chemoepitaxial Template" @default.
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• W2321983323 doi "https://doi.org/10.1021/ma500429x" @default.
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