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• W2322006467 abstract "A family of supramolecular four-component nanorotors was quantitatively self-assembled from two different zinc(II) porphyrins: one representing the stator and the other the rotator with DABCO as an interconnecting axle and copper(I) ions. Rotational spinning in ROT-1′ occurs at 97 000 s–1 at 25 °C but is virtually stopped at −75 °C. The activation vs binding data suggest that spinning is an intrasupramolecular process occurring to >99.9% without dissociation. Addition and removal of two further equiv of Cu+ reversibly switches the mode of the stochastic rotation between pure 180° and mixed 90°/180° steps and reversibly regulates the speed between 97 000 and ∼80 000 s–1." @default.
• W2322006467 created "2016-06-24" @default.
• W2322006467 creator A5051082150 @default.
• W2322006467 creator A5026089886 @default.
• W2322006467 date "2013-12-09" @default.
• W2322006467 modified "2023-09-25" @default.
• W2322006467 title "Four-Component Supramolecular Nanorotors" @default.
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• W2322006467 doi "https://doi.org/10.1021/ja411011a" @default.
• W2322006467 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24299448" @default.
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