Matches in SemOpenAlex for { <https://semopenalex.org/work/W2322009966> ?p ?o ?g. }
- W2322009966 endingPage "2730" @default.
- W2322009966 startingPage "2720" @default.
- W2322009966 abstract "Structurally well-defined stereoregular diblock copolymers composed of syndiotactic polyallyltrimethylsilane (sPATMS) and poly(methyl methacrylate) (PMMA) were prepared by using an α-bromoester-terminated sPATMS macroinitiator, which was chain extended by MMA using a cuprous halide-based atom transfer radical polymerization (ATRP) system. The α-bromoester-terminated sPATMS macroinitiator was prepared via the esterfication of hydroxyl-capped sPATMS with α-bromoisobutyryl bromide. The hydroxyl-capped sPATMS was generated via a selective chain transfer reaction to triethylaluminum (TEA) during the syndiospecific polymerization of allyltrimethylsilane (ATMS) conducted in the presence of syndiospecific ansa-metallocene catalysts. The proposed synthetic route not only offers the high-yield production of stereoregular sPATMS-b-PMMA but also provides the linking of the stereoregular block (sPATMS) with PMMA through a controlled/living radical polymerization process. Moreover, the proposed method offers effective control over the block chain length, the molecular weight distribution (Mw/Mn) and the stereoregularity of sPATMS block. Thus, the self-assembly of the resultant diblock copolymers produces well-ordered nanostructures from microphase separation, as evidenced by transmission electron microscopy and small-angle X-ray scattering results." @default.
- W2322009966 created "2016-06-24" @default.
- W2322009966 creator A5005727953 @default.
- W2322009966 creator A5009277466 @default.
- W2322009966 creator A5024393271 @default.
- W2322009966 creator A5027510105 @default.
- W2322009966 creator A5049728261 @default.
- W2322009966 creator A5051244699 @default.
- W2322009966 creator A5058231593 @default.
- W2322009966 creator A5061440149 @default.
- W2322009966 creator A5090117926 @default.
- W2322009966 date "2012-03-13" @default.
- W2322009966 modified "2023-09-26" @default.
- W2322009966 title "Syndiotactic Polyallyltrimethylsilane-Based Stereoregular Diblock Copolymers: Syntheses and Self-Assembled Nanostructures" @default.
- W2322009966 cites W1965302901 @default.
- W2322009966 cites W1966168202 @default.
- W2322009966 cites W1966479408 @default.
- W2322009966 cites W1966926504 @default.
- W2322009966 cites W1967288744 @default.
- W2322009966 cites W1969364668 @default.
- W2322009966 cites W1969766958 @default.
- W2322009966 cites W1970953120 @default.
- W2322009966 cites W1971549569 @default.
- W2322009966 cites W1972419820 @default.
- W2322009966 cites W1975869101 @default.
- W2322009966 cites W1975899172 @default.
- W2322009966 cites W1976460414 @default.
- W2322009966 cites W1977970573 @default.
- W2322009966 cites W1981797861 @default.
- W2322009966 cites W1983346802 @default.
- W2322009966 cites W1984659595 @default.
- W2322009966 cites W1985376590 @default.
- W2322009966 cites W1985945912 @default.
- W2322009966 cites W1986025973 @default.
- W2322009966 cites W1986665928 @default.
- W2322009966 cites W1989085228 @default.
- W2322009966 cites W1990150561 @default.
- W2322009966 cites W1990232537 @default.
- W2322009966 cites W1993265084 @default.
- W2322009966 cites W1993266500 @default.
- W2322009966 cites W1994571297 @default.
- W2322009966 cites W1995523725 @default.
- W2322009966 cites W1996477114 @default.
- W2322009966 cites W1997665099 @default.
- W2322009966 cites W1998348282 @default.
- W2322009966 cites W1999684450 @default.
- W2322009966 cites W2000687277 @default.
- W2322009966 cites W2000896867 @default.
- W2322009966 cites W2001338086 @default.
- W2322009966 cites W2001382215 @default.
- W2322009966 cites W2001989169 @default.
- W2322009966 cites W2004610614 @default.
- W2322009966 cites W2005139687 @default.
- W2322009966 cites W2005919018 @default.
- W2322009966 cites W2009162008 @default.
- W2322009966 cites W2010764429 @default.
- W2322009966 cites W2013232487 @default.
- W2322009966 cites W2015488254 @default.
- W2322009966 cites W2016123905 @default.
- W2322009966 cites W2016927114 @default.
- W2322009966 cites W2022381162 @default.
- W2322009966 cites W2022965433 @default.
- W2322009966 cites W2024132914 @default.
- W2322009966 cites W2025502470 @default.
- W2322009966 cites W2026132129 @default.
- W2322009966 cites W2027735574 @default.
- W2322009966 cites W2031993188 @default.
- W2322009966 cites W2035994280 @default.
- W2322009966 cites W2037056313 @default.
- W2322009966 cites W2040006835 @default.
- W2322009966 cites W2040415177 @default.
- W2322009966 cites W2041038944 @default.
- W2322009966 cites W2042654781 @default.
- W2322009966 cites W2044461296 @default.
- W2322009966 cites W2047722355 @default.
- W2322009966 cites W2048035279 @default.
- W2322009966 cites W2049937065 @default.
- W2322009966 cites W2051330366 @default.
- W2322009966 cites W2052336863 @default.
- W2322009966 cites W2055190835 @default.
- W2322009966 cites W2056173237 @default.
- W2322009966 cites W2057871431 @default.
- W2322009966 cites W2058827055 @default.
- W2322009966 cites W2061465503 @default.
- W2322009966 cites W2062403170 @default.
- W2322009966 cites W2062666119 @default.
- W2322009966 cites W2062832130 @default.
- W2322009966 cites W2069507241 @default.
- W2322009966 cites W2071635280 @default.
- W2322009966 cites W2074475195 @default.
- W2322009966 cites W2078512206 @default.
- W2322009966 cites W2079976383 @default.
- W2322009966 cites W2080348029 @default.
- W2322009966 cites W2080731876 @default.
- W2322009966 cites W2081584642 @default.
- W2322009966 cites W2084073071 @default.
- W2322009966 cites W2084787480 @default.
- W2322009966 cites W2085554061 @default.