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- W2322052401 abstract "The inert cations that accompany the anionic dithiolato complexes, Ni(L)22−(L = S2C2(CN)2, S2C:C(CN)2, S2C:NCN, S2C:C(COOCH3)2, S2C:C(COOC2H5)2, and S2C:N(C6H5) are readily replaced by the coordinately unsaturated M′(P(C6H5)3)2+ (M′ = Ag(I), Cu(I)) complex cations. The i.r. spectra of the crystalline polynuclear complexes Ni(L)2[(P(C6H5)3)nM′]2 (n = 2 or 3) thus obtained indicate that the anion-cation interactions occur primarily through the mercapto groups. In the Ni(S2C:N(C6H5))2[P(C6H5)3)3Cu]2 complex the copper is coordinated to the carbimate nitrogen of the ligand. Interactions of Cu(P(C6H5)3)2+ with the Ni(S2C2(CN)2)2 −2 and Ni(S2C:C(CN)2)22− complexes appear to occur with the π-system of the nitrile groups of the complex ligands. Dinuclear complexes of the composition [M′(P(C6H5)3)2]2L also were obtained and their structures and properties are discussed." @default.
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- W2322052401 date "1975-10-01" @default.
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- W2322052401 title "Metal complexes as ligands—VI" @default.
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- W2322052401 doi "https://doi.org/10.1016/0022-1902(75)80834-7" @default.
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