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- W2322144039 abstract "Fluorinated Fe-porphyrins, especially [tetrakis(pentafluorophenyl)porphyrinato]iron(III) chloride (tetrakis(pentafluorophenyl)porphyrinato = TPFPP) (TPFPP)FeCl (Fepor-2a), were found to be highly efficient for catalyzing the double epoxidation of divinylbenzene (DVB) to divinylbenzene dioxide (DVBDO), a novel component of epoxy resin formulation. The electronic properties of the catalysts are highly dependent on the substituents on the phenyl groups of these metalloporphyrins. The electron-rich fluorinated Fe-porphyrins are more selective toward epoxidation but are more vulnerable toward decomposition in H2O2. On the other hand, the electron deficient Fe-porphyrins are more stable, yet more Lewis acidic, which facilitates the formation of byproducts such as epoxide ring opening and overoxidation." @default.
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- W2322144039 date "2015-01-13" @default.
- W2322144039 modified "2023-10-16" @default.
- W2322144039 title "Epoxidation of the Commercially Relevant Divinylbenzene with [<i>tetrakis</i>-(Pentafluorophenyl)porphyrinato]iron(III) Chloride and Its Derivatives" @default.
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- W2322144039 doi "https://doi.org/10.1021/ie504550p" @default.
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