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• W2322236476 abstract "Propargyl aldehydes underwent isomerization to allenyl aldehydes under mildly basic conditions when complexed to an organo-manganese auxiliary using methylcyclopentadienyl manganese tricarbonyl (MMT). This traceless auxiliary magnifies the axial chirality of the allene moiety, allowing for highly diastereoselective additions to the aldehyde carbonyl and subsequent access to an array of 2,3-allenols. Using this strategy, a nitrile-substituted 2,3-allenol was prepared and efficiently converted to Hagen’s gland lactone." @default.
• W2322236476 created "2016-06-24" @default.
• W2322236476 creator A5029360822 @default.
• W2322236476 creator A5060550569 @default.
• W2322236476 creator A5085514685 @default.
• W2322236476 date "2015-02-09" @default.
• W2322236476 modified "2023-09-23" @default.
• W2322236476 title "Organo-Manganese η²-Auxiliary Directed Reactions: A Diastereoselective Approach to 2,3-Allenols" @default.
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• W2322236476 doi "https://doi.org/10.1021/ol503757h" @default.
• W2322236476 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4537065" @default.
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• W2322236476 hasPublicationYear "2015" @default.
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