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• W2322259610 abstract "The recent discovery of a synthetic method for chemically reactive {001} facet-dominating TiO2 nanoparticles using hydrofluoric acid provided a new aspect of interfacial chemistry in photo catalysts, batteries, and photoelectrochemical cells using TiO2. We reveal the effects of the reactive {001} facet on the photoexcited charge transfer from organic fluorophores, 9-substituted anthracene derivatives (An–X; X = H and COOH) and tetracene, to TiO2 nanoparticles by differing the fraction of {001} facet. The kinetic analysis of the fluorescence quenching by TiO2 nanoparticles based on Stern–Volmer relation is employed to estimate the quenching rate constant as a function of the fraction of {001} facet. The results imply a significant enhancement of the photoexcited charge transfer from fluorophores to TiO2 nanoparticles by the reactive {001} facet with a factor of more than 10 in the quenching rate constant at maximum." @default.
• W2322259610 created "2016-06-24" @default.
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• W2322259610 date "2011-10-06" @default.
• W2322259610 modified "2023-10-16" @default.
• W2322259610 title "Enhancement of Photoexcited Charge Transfer by {001} Facet-Dominating TiO₂ Nanoparticles" @default.
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• W2322259610 doi "https://doi.org/10.1021/jz2011622" @default.
• W2322259610 hasPublicationYear "2011" @default.
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