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- W2322320891 abstract "A brownmillerite SrFeO2.5 thin film grown on a SrTiO3(001) substrate contained an a-axis-oriented single-crystalline domain near the substrate and multiple domains with three orthogonal orientations. When the film was reduced with CaH2, it changed topotactically to a homogeneous c-axis-oriented infinite-layer structure, SrFeO2. A brownmillerite SrFeO2.5 thin film grown on a SrTiO3(111) substrate and treated with CaH2 at 250 °C also changed to (111)-oriented SrFeO2 with an infinite-layer structure. During reduction at low temperatures, the framework of the perovskite-structure stays intact, some oxygen atoms are removed from it, and others are rearranged." @default.
- W2322320891 created "2016-06-24" @default.
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- W2322320891 date "2010-10-13" @default.
- W2322320891 modified "2023-10-14" @default.
- W2322320891 title "Topotactic Changes in Thin Films of Brownmillerite SrFeO<sub>2.5</sub> Grown on SrTiO<sub>3</sub> Substrates to Infinite-Layer Structure SrFeO<sub>2</sub>" @default.
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- W2322320891 doi "https://doi.org/10.1021/cg101133w" @default.
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