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- W2322463614 abstract "The redox behavior of the series of 7-substituted 6-oxo-6,9-dihydro[1,2,5]selenadiazolo[3,4-h]quinolines and 8-substituted 9-oxo-6,9-dihydro[1,2,5]selenadiazolo[3,4-f]quinolines with R7, R8 = H, COOC2H5, COOCH3, COOH, COCH3, and CN has been studied by in situ EPR and EPR/UV–vis spectroelectrochemistry in dimethylsulfoxide. All selenadiazoloquinolones undergo a one-electron reduction process to form the corresponding radical anions. Their stability strongly depends on substitution at the nitrogen atom of the 4-pyridone ring. The primary generated radical anions from N-ethyl-substituted quinolones are stable, whereas for the quinolones with imino hydrogen, the initial radical anions rapidly dimerize to produce unusually stable sigma-dimer (σ-dimer) dianions. These are reversibly oxidized to the initial compounds at potentials considerably less negative than the original reduction process in the back voltammetric scan. The dimer dianion can be further reduced to the stable paramagnetic dimer radical trianion in the region of the second reversible reduction step. The proposed complex reaction mechanism was confirmed by in situ EPR/UV–vis cyclovoltammetric experiments. The site of the dimerization in the σ-dimer and the mapping of the unpaired spin density both for radical anions and σ-dimer radical trianions with unusual unpaired spin distribution have been assigned by means of density functional theory calculations." @default.
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- W2322463614 date "2012-09-27" @default.
- W2322463614 modified "2023-09-26" @default.
- W2322463614 title "Stable Radical Trianions from Reversibly Formed Sigma-Dimers of Selenadiazoloquinolones Studied by In Situ EPR/UV–vis Spectroelectrochemistry and Quantum Chemical Calculations" @default.
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- W2322463614 doi "https://doi.org/10.1021/jp307270b" @default.
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