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- W2322552862 endingPage "6372" @default.
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- W2322552862 abstract "The functional poly(2-dimethylaminoethyl methacrylate) (PDMAEMA) brush was grafted onto the alkyl-bromide-modified magnetite/silica/poly(N,N′-methylenebisacrylamide-co-2-hydroxyethylmethacrylate) (Fe3O4@SiO2@PHEMA) trilayer microspheres via the surface-induced atom transfer radical polymerization. Fe3O4@SiO2@PHEMA trilayer microspheres with surface alkyl bromide groups were prepared by the combination of sol–gel process for the synthesis of Fe3O4@SiO2 core–shell inorganic component and distillation–precipitation polymerization for the formation of PHEMA shell together with the subsequent esterification of the surface hydroxyl group and 2-bromoisobutyryl bromide. Furthermore, the gold nanoparticles were facilely loaded into the functional PDMAEMA brushes through the in situ reduction due to their strong coordinate interaction. These PDMAEMA brush-stabilized gold nanocolloids were used as a catalyst with the reduction of 4-nitophenol to 4-aminophenol as a model reaction, which revealed a highly catalytic efficiency and good reusable property." @default.
- W2322552862 created "2016-06-24" @default.
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- W2322552862 date "2013-03-15" @default.
- W2322552862 modified "2023-09-27" @default.
- W2322552862 title "Multilayer Magnetic Composite Particles with Functional Polymer Brushes as Stabilizers for Gold Nanocolloids and Their Recyclable Catalysis" @default.
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- W2322552862 doi "https://doi.org/10.1021/jp311467b" @default.
- W2322552862 hasPublicationYear "2013" @default.
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