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• W2322586136 abstract "We report the isolation and structural characterization of an octaneselenolate-protected Au25 cluster ([Au25(SeC8H17)18]−). Isolated [Au25(SeC8H17)18]− was characterized by various analytical techniques. The results strongly suggest that [Au25(SeC8H17)18]− possesses a similar geometric structure to the well-studied thiolate (RS)-protected Au25 cluster ([Au25(SR)18]−) and that the charge transfer between the metal atoms and ligands in [Au25(SeC8H17)18]− is lower than that in [Au25(SR)18]−. To the best of our knowledge, this is the first report of the isolation of a selenolate-protected gold cluster. [Au25(SeC8H17)18]− is an ideal compound for determining how changing the ligand from thiolate to selenolate affects the fundamental properties of a cluster." @default.
• W2322586136 created "2016-06-24" @default.
• W2322586136 creator A5010122581 @default.
• W2322586136 creator A5043613374 @default.
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• W2322586136 date "2011-09-23" @default.
• W2322586136 modified "2023-10-11" @default.
• W2322586136 title "Isolation and Structural Characterization of an Octaneselenolate-Protected Au₂₅ Cluster" @default.
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• W2322586136 doi "https://doi.org/10.1021/la203301p" @default.
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