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• W2322651495 endingPage "15929" @default.
• W2322651495 startingPage "15926" @default.
• W2322651495 abstract "Catalytic activation of an unstrained, unactivated Si–C(sp3) bond in water to form methane and silanol by electrophilic rhodium(III) porphyrin [(por)RhIII] in acidic aqueous solutions under visible light (λ ≥ 420 nm) has been developed. Activation of the Si–C(sp3) bond occurs through direct Si–C bond cleavage, with methyl group transfer to rhodium to give a porphyrin rhodium methyl complex. Photolysis of (por)Rh-CH3 in water yields methyl radical and (por)RhII. Subsequently, (por)RhII reacts with water rapidly to produce (por)Rh-H and (por)Rh-OH. (por)Rh-OH is then protonated to regenerate (por)RhIII-OH2, and (por)Rh-H undergoes hydrogen atom abstraction by methyl radical to form the observed methane." @default.
• W2322651495 created "2016-06-24" @default.
• W2322651495 creator A5049418493 @default.
• W2322651495 creator A5051474305 @default.
• W2322651495 date "2011-09-21" @default.
• W2322651495 modified "2023-10-18" @default.
• W2322651495 title "Visible Light Promoted Hydroxylation of a Si–C(sp³) Bond Catalyzed by Rhodium Porphyrins in Water" @default.
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• W2322651495 doi "https://doi.org/10.1021/ja207468n" @default.
• W2322651495 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21919487" @default.
• W2322651495 hasPublicationYear "2011" @default.
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