Matches in SemOpenAlex for { <https://semopenalex.org/work/W2322676504> ?p ?o ?g. }
- W2322676504 endingPage "3242" @default.
- W2322676504 startingPage "3239" @default.
- W2322676504 abstract "Under an atmosphere of CO, the Mo(IV) imido complex Cp*Mo[N(iPr)C(Me)N(iPr)](NSiMe3) (Cp* = η5-C5Me5) (1) serves as a catalyst for production of an isocyanate via metal-mediated nitrene group transfer in benzene solution under mild conditions (55 °C, 10 psi) according to RN3 + CO → N2 + RNCO. Mechanistic and structural studies support a catalytic cycle for nitrene group transfer involving formal Mo(II) monocarbonyl and Mo(IV) (κ2-C,N)-isocyanate intermediates. These results complement an earlier finding that catalytic production of isocyanates can alternatively proceed through oxygen-atom transfer and an isomeric Mo(IV) (κ2-C,O)-isocyanate according to N2O + CNR → N2 + RNCO." @default.
- W2322676504 created "2016-06-24" @default.
- W2322676504 creator A5031106218 @default.
- W2322676504 creator A5034964331 @default.
- W2322676504 creator A5038634037 @default.
- W2322676504 creator A5052294304 @default.
- W2322676504 creator A5072361229 @default.
- W2322676504 date "2014-06-26" @default.
- W2322676504 modified "2023-10-03" @default.
- W2322676504 title "Catalytic Production of Isocyanates via Orthogonal Atom and Group Transfers Employing a Shared Formal Group 6 M(II)/M(IV) Redox Cycle" @default.
- W2322676504 cites W1979289650 @default.
- W2322676504 cites W1981255128 @default.
- W2322676504 cites W1983772602 @default.
- W2322676504 cites W1992340425 @default.
- W2322676504 cites W1993927654 @default.
- W2322676504 cites W2003431221 @default.
- W2322676504 cites W2014996990 @default.
- W2322676504 cites W2019169667 @default.
- W2322676504 cites W2021501811 @default.
- W2322676504 cites W2021657198 @default.
- W2322676504 cites W2022697983 @default.
- W2322676504 cites W2027822744 @default.
- W2322676504 cites W2031009106 @default.
- W2322676504 cites W2036172610 @default.
- W2322676504 cites W2065982719 @default.
- W2322676504 cites W2073030296 @default.
- W2322676504 cites W2073699437 @default.
- W2322676504 cites W2085918440 @default.
- W2322676504 cites W2094112103 @default.
- W2322676504 cites W2103490052 @default.
- W2322676504 cites W2113163897 @default.
- W2322676504 cites W2124650942 @default.
- W2322676504 cites W2126205614 @default.
- W2322676504 cites W2142040356 @default.
- W2322676504 cites W2144280675 @default.
- W2322676504 cites W2319591706 @default.
- W2322676504 cites W2320619856 @default.
- W2322676504 cites W2332586524 @default.
- W2322676504 doi "https://doi.org/10.1021/om500532s" @default.
- W2322676504 hasPublicationYear "2014" @default.
- W2322676504 type Work @default.
- W2322676504 sameAs 2322676504 @default.
- W2322676504 citedByCount "17" @default.
- W2322676504 countsByYear W23226765042014 @default.
- W2322676504 countsByYear W23226765042015 @default.
- W2322676504 countsByYear W23226765042016 @default.
- W2322676504 countsByYear W23226765042017 @default.
- W2322676504 countsByYear W23226765042018 @default.
- W2322676504 countsByYear W23226765042020 @default.
- W2322676504 countsByYear W23226765042021 @default.
- W2322676504 countsByYear W23226765042022 @default.
- W2322676504 crossrefType "journal-article" @default.
- W2322676504 hasAuthorship W2322676504A5031106218 @default.
- W2322676504 hasAuthorship W2322676504A5034964331 @default.
- W2322676504 hasAuthorship W2322676504A5038634037 @default.
- W2322676504 hasAuthorship W2322676504A5052294304 @default.
- W2322676504 hasAuthorship W2322676504A5072361229 @default.
- W2322676504 hasConcept C155647269 @default.
- W2322676504 hasConcept C161790260 @default.
- W2322676504 hasConcept C178790620 @default.
- W2322676504 hasConcept C185592680 @default.
- W2322676504 hasConcept C188027245 @default.
- W2322676504 hasConcept C2777691172 @default.
- W2322676504 hasConcept C2779578285 @default.
- W2322676504 hasConcept C2780534471 @default.
- W2322676504 hasConcept C2781311116 @default.
- W2322676504 hasConcept C2994492776 @default.
- W2322676504 hasConcept C32909587 @default.
- W2322676504 hasConcept C38489247 @default.
- W2322676504 hasConcept C63338738 @default.
- W2322676504 hasConcept C71240020 @default.
- W2322676504 hasConceptScore W2322676504C155647269 @default.
- W2322676504 hasConceptScore W2322676504C161790260 @default.
- W2322676504 hasConceptScore W2322676504C178790620 @default.
- W2322676504 hasConceptScore W2322676504C185592680 @default.
- W2322676504 hasConceptScore W2322676504C188027245 @default.
- W2322676504 hasConceptScore W2322676504C2777691172 @default.
- W2322676504 hasConceptScore W2322676504C2779578285 @default.
- W2322676504 hasConceptScore W2322676504C2780534471 @default.
- W2322676504 hasConceptScore W2322676504C2781311116 @default.
- W2322676504 hasConceptScore W2322676504C2994492776 @default.
- W2322676504 hasConceptScore W2322676504C32909587 @default.
- W2322676504 hasConceptScore W2322676504C38489247 @default.
- W2322676504 hasConceptScore W2322676504C63338738 @default.
- W2322676504 hasConceptScore W2322676504C71240020 @default.
- W2322676504 hasIssue "13" @default.
- W2322676504 hasLocation W23226765041 @default.
- W2322676504 hasOpenAccess W2322676504 @default.
- W2322676504 hasPrimaryLocation W23226765041 @default.
- W2322676504 hasRelatedWork W1967533796 @default.
- W2322676504 hasRelatedWork W1976758209 @default.
- W2322676504 hasRelatedWork W2010368168 @default.
- W2322676504 hasRelatedWork W2143287661 @default.
- W2322676504 hasRelatedWork W2322676504 @default.
- W2322676504 hasRelatedWork W2323923022 @default.
- W2322676504 hasRelatedWork W2384573759 @default.
- W2322676504 hasRelatedWork W2395437815 @default.
- W2322676504 hasRelatedWork W2954196359 @default.