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• W2322841128 abstract "Peptide mimics with constrained backbone and side-chain geometry are important tools for studying structure activity relationships of biologically active candidates. A general method for creating β-turn mimics possessing side-chain diversity has been developed featuring diastereoselective S(N)1 displacements of an iodide precursor. In particular, 6-iodo-pyrroloazepin-2-one amino ester 10 has served as a common precursor in reactions with a variety of alcohol, phenol, nitrate, and azide nucleophiles to provide an array of constrained peptide mimics." @default.
• W2322841128 created "2016-06-24" @default.
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• W2322841128 date "2011-06-22" @default.
• W2322841128 modified "2023-10-13" @default.
• W2322841128 title "Mimics of Peptide Turn Backbone and Side-Chain Geometry by a General Approach for Modifying Azabicyclo[5.3.0]alkanone Amino Acids" @default.
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• W2322841128 doi "https://doi.org/10.1021/jo2006363" @default.
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