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- W2322860136 abstract "The ternary arsenides RE 2/3 Zn 2 As 2 (RE = La, Ce, Pr, Nd, Sm) were synthesized from the elements in NaCl/KCl salt fluxes and were characterized by powder X-ray diffraction. The Ce 2/3 Zn 2 As 2 structure was refined on the basis of single-crystal X-ray diffractometer data: CaAl 2 Si 2 type, P¯3m1, Z = 1, a = 417.17(6), c = 703.7(1) pm, wR2 = 0.0353, 211 F 2 values, 11 variables, SOF(Ce) = 62.9(5) %. The zinc and arsenic atoms form a two-dimensional network of edge-sharing ZnAs 4/4 tetrahedra with Zn-As distances of 253 pm. These covalently bonded [Zn 2 As 2 ] 2 − layers are separated and charge-balanced by the cerium atoms. Each cerium atom has a slightly distorted octahedral arsenic coordination (Ce-As 302 pm). The defect type of the RE 2/3 Zn 2 As 2 arsenides is discussed with respect to isotypic sulfides RE 2/3 Cu 2 S 2 ." @default.
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- W2322860136 date "2011-03-01" @default.
- W2322860136 modified "2023-09-30" @default.
- W2322860136 title "CaAl<sub>2</sub>Si<sub>2</sub>-type Arsenides RE<sub>2/3</sub>Zn<sub>2</sub>As<sub>2</sub> (RE = La, Ce, Pr, Nd, Sm)" @default.
- W2322860136 doi "https://doi.org/10.1515/znb-2011-0302" @default.
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