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• W2322895169 abstract "Two linear isomers, OPN and ONP, were formed in an Ar matrix at 16 K by ArF laser (λ = 193 nm) photolysis of phosphoryl triazide, OP(N3)3, and comprehensively characterized by their mid- and far-IR spectra as well as 14/15N isotopic data. Two intermediates, (N3)2P(O)N and N3P(O)N4, have been isolated in an Ar matrix and spectroscopically characterized. Photolysis of these intermediates using near-UV/vis light (λ > 320 nm) was shown to yield exclusively ONP, which under ArF laser irradiation selectively photo-isomerized to OPN. The photochemical and molecular properties of OPN and ONP are discussed on the basis of experimental and ab initio calculated results." @default.
• W2322895169 created "2016-06-24" @default.
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• W2322895169 date "2011-12-02" @default.
• W2322895169 modified "2023-09-25" @default.
• W2322895169 title "Elusive O═P≡N, a Rare Example of Phosphorus σ²λ⁵-Coordination" @default.
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• W2322895169 doi "https://doi.org/10.1021/ja2091867" @default.
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