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- W2322961574 abstract "Inorganic nitrates in solid deposits were detected directly by ambient-pressure helium-plasma ionization-mass spectrometry (HePI-MS), without the need for extensive sample preparation. Nitrates were detected even from complex matrices such as meats and fruit juices. Any electrospray-ionization mass spectrometer can be modified to perform ambient-pressure HePI-MS by simply passing helium through the metal capillary intended for liquid-sample delivery. Nitrates on paper strips, glass slides, or cotton swabs (sometimes wetted with a mineral acid) were inserted directly into the ambient-pressure HePI source. The spectra acquired under negative-ion generating conditions showed a peak at m/z 62 for the nitrate ion, along with a lower-intensity peak at m/z 125 for the nitrate adduct of nitric acid. Apparently, it is nitric acid that is initially transferred to the gas phase, forming an ion–molecule complex with hydroxyl anions present in the plasma. The ion-neutral complex then dissociates by eliminating water to produce gaseous NO3– ions. This hypothesis was supported by the observation that certain solid nitrate salts, which were not readily amenable to HePI (notably the alkali nitrates), were immediately detected as m/z 62 and 125 ions upon acidification by a strong acid. Quantitative evaluations showed that the nitrate-signal response versus the deposited mass is linear for over 3 orders of magnitude. With the use of 15N-labeled nitrate (m/z 63), the limit of detection was determined to be as low as 200 fg." @default.
- W2322961574 created "2016-06-24" @default.
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- W2322961574 date "2012-12-11" @default.
- W2322961574 modified "2023-10-16" @default.
- W2322961574 title "Direct Detection of Inorganic Nitrate Salts by Ambient Pressure Helium-Plasma Ionization Mass Spectrometry" @default.
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- W2322961574 doi "https://doi.org/10.1021/ac3026916" @default.
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