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- W2323073899 abstract "Unprecedented divergent rearrangements of cyclopropyl-substituted fluoroepoxides are reported. In the presence of a catalytic amount of benzoic acid, cyclopropyl-substituted fluoroepoxides efficiently undergo 1,5-fluorine migration. However, when the fluoroepoxides are heated with K2CO3 at 60 °C, 1,2-fluorine migration occurs. The 1,5-fluorine migration is believed to proceed via a carbocation intermediate, while the 1,2-fluorine migration may involve a tight ion pair intermediate or proceed via a concerted process." @default.
- W2323073899 created "2016-06-24" @default.
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- W2323073899 date "2014-01-14" @default.
- W2323073899 modified "2023-10-07" @default.
- W2323073899 title "Divergent Rearrangements of Cyclopropyl-Substituted Fluoroepoxides Involving C–F Bond Cleavage and Formation" @default.
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- W2323073899 doi "https://doi.org/10.1021/ol403644n" @default.
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