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- W2323084795 abstract "Site-selective emission spectra of Eu3+-doped CeO2 nanoparticles up to the 5D0–7F5 transition were recorded under cryogenic conditions to identify the local structure around the Eu3+ dopants in ceria. It is found that pretreatment conditions are crucial for the redistribution of dopants from a broad variety of environments to six well-defined lattice sites. The influence of the dopant and the host structure on the catalytic activity was investigated. A relationship between structure and reactivity is discussed. It is shown that oxygen transport is most efficient in particles with a pronounced amorphous character." @default.
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- W2323084795 date "2014-09-30" @default.
- W2323084795 modified "2023-10-11" @default.
- W2323084795 title "High-Resolution Spectroscopy of Europium-Doped Ceria as a Tool To Correlate Structure and Catalytic Activity" @default.
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- W2323084795 doi "https://doi.org/10.1021/jp505467r" @default.
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