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- W2323177712 abstract "The quality and temperature stability of 1 nm Bi2Te3/5 nm Sb2Te3 superlattices prepared by molecular beam epitaxy for the first time was investigated by in situ and ex situ X-ray diffraction and transmission electron microscopy. Upon heating, the superlattice structures are not stable against interdiffusion of the components, with micro- and nanostructural changes occurring at temperatures as low as 200 °C. The interdiffusion preferably starts next to superlattice defects. At 300 °C the Bi2Te3 and Sb2Te3 layers were mostly interdiffused, forming the thermodynamically stable Sb1.66Bi0.33Te3 alloy. The data suggests that structural integrity of Bi2Te3/Sb2Te3 superlattices will not be stable for extended times above 200 °C, thus inhibiting application of such superlattices over a wide temperature range." @default.
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- W2323177712 date "2014-11-12" @default.
- W2323177712 modified "2023-10-18" @default.
- W2323177712 title "Synthesis and Thermal Instability of High-Quality Bi<sub>2</sub>Te<sub>3</sub>/Sb<sub>2</sub>Te<sub>3</sub> Superlattice Thin Film Thermoelectrics" @default.
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- W2323177712 doi "https://doi.org/10.1021/cm5031574" @default.
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