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- W2323201351 abstract "We studied the preparation and circular dichroism (CD) behavior of 2,6-pyridylene ethynylene octameric oligomer linked to a β-d-glucoside moiety with a C20-alkylene chain. The addition of Cu(OTf)2 salt led to a remarkable enhancement of the first CD band of the oligomer, and an unexpected concentration and time dependency were observed. For example, when 1.0 × 10–3 M of Cu(OTf)2 was added to a 1,2-dichloroethane solution of the oligomer (5.0 × 10–4 M, unit concentration), the CD band appeared in the positive at first and gradually inverted into the negative with time." @default.
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- W2323201351 date "2012-05-18" @default.
- W2323201351 modified "2023-09-25" @default.
- W2323201351 title "Concentration- and Time-Dependent Eccentric Changes in Circular Dichroism of Saccharide-Linked Ethynylpyridine Oligomer with Copper(II) Ions" @default.
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- W2323201351 doi "https://doi.org/10.1021/jo300735j" @default.
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