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• W2323221572 abstract "A new tricyanoferrate(III) building block and a trinuclear single-molecule magnet derivative are described. The treatment of a 2:1 ratio of [NEt4][(Tp*Bn)FeIII(CN)3]·H2O·MeOH [1; Tp*Bn = tris(3,5-dimethyl-4-benzyl)pyrazolylborate] with nickel(II) trifluoromethanesulfonate gives {[(Tp*Bn)FeIII(CN)3]2[NiII(DMF)4]}·2DMF (2; DMF = N,N-dimethylformamide). The symmetry-equivalent FeIIILS ions lead to a favorable alignment of anisotropy tensors (i.e., Fe···B axes) in 2, and an energy barrier of Δeff/kB = 16.7 K is found for the ST = 2 complex." @default.
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• W2323221572 date "2011-09-27" @default.
• W2323221572 modified "2023-10-10" @default.
• W2323221572 title "Pyrazolylborates and Their Importance in Tuning Single-Molecule Magnet Properties of {Fe^III₂Ni^II} Complexes" @default.
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• W2323221572 doi "https://doi.org/10.1021/ic2017825" @default.
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