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• W2323282552 abstract "We have observed and investigated the ultrafast self-assembly of 1-adamantanethiol (AdSH) molecules on gold at room temperature and at 393K by scanning tunneling microscopy and X-ray photoelectron spectroscopy. Rapid high-temperature adsorption was shown to yield a well-ordered defect-free hexagonal packed layer of AdSH molecules. The demonstrated subsecond self-assembly dramatically reduces the time required to form such a layer and provides an impetus to expand the application of self-assembled monolayers in areas, such as surface passivation/functionalization, sensors, catalysis, and electronics. The chemisorbed AdSH molecules have been investigated at a single-molecule level using ambient STM. Near atomic resolution STM images allowed the determination of the preferred molecular conformation on the gold and the molecular tilt (114°) and the twist (0°) angles. On the basis of these findings, a detailed molecular model for assembled AdSH molecules on gold is proposed." @default.
• W2323282552 created "2016-06-24" @default.
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• W2323282552 date "2010-10-25" @default.
• W2323282552 modified "2023-09-25" @default.
• W2323282552 title "Subsecond Self-Assembled Monolayer Formation" @default.
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• W2323282552 doi "https://doi.org/10.1021/jp106289p" @default.
• W2323282552 hasPublicationYear "2010" @default.
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