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- W2323383440 abstract "The distributions of electron-transfer dynamics in dye-sensitized TiO2 films are probed using single-molecule microscopy. The time-dependent emission (i.e., blinking dynamics) of rhodamine 6G (R6G) and rhodamine B (RB) sensitized TiO2 films are quantified by constructing cumulative distribution functions of emissive (“on”) and nonemissive (“off”) events. Maximum likelihood estimation (MLE) methods and quantitative goodness-of-fit tests based on the Kolmogorov–Smirnov (KS) statistics are used to establish the best fit to the photophysical data. The on-time distributions for R6G and RB on TiO2 are fit by power laws, but only for emissive durations that last longer than ∼0.7 s. Furthermore, large variations in the power-law exponents are observed when using least-squares fitting as compared to the combined MLE and KS-test approach. The off-time distributions for molecules on TiO2 and glass are not consistent with power laws and are instead well represented by log-normal distributions. Our observations suppor..." @default.
- W2323383440 created "2016-06-24" @default.
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- W2323383440 date "2013-10-03" @default.
- W2323383440 modified "2023-10-14" @default.
- W2323383440 title "Dispersive Electron-Transfer Kinetics from Single Molecules on TiO<sub>2</sub> Nanoparticle Films" @default.
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- W2323383440 doi "https://doi.org/10.1021/jp405899v" @default.
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