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- W2323389969 abstract "An efficient strategy for the synthesis of a variety of 3-substituted isocoumarins has been developed. The reaction proceeded from o-halobenzoic acids and 1,3-diketones via a copper(I)-catalyzed domino reaction in DMF under the action of K(3)PO(4) at 90-120 °C without a ligand to afford the corresponding 3-substituted isocoumarin derivatives in good to excellent yields. o-Halobenzoic acids could be o-iodobenzoic acid, o-bromobenzoic acid, and o-chlorobenzoic acid derivatives. 1,3-Diketones could be alkyl- and aryl-substituted 1,3-diketones." @default.
- W2323389969 created "2016-06-24" @default.
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- W2323389969 date "2012-02-14" @default.
- W2323389969 modified "2023-10-17" @default.
- W2323389969 title "Assembly of 3-Substituted Isocoumarins via a CuI-Catalyzed Domino Coupling/Addition/Deacylation Process" @default.
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- W2323389969 doi "https://doi.org/10.1021/jo2026433" @default.
- W2323389969 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22300252" @default.
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