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- W2323407632 abstract "We have studied the photodissociation dynamics of anisole (C6H5OCH3) at 193 nm and determined the absolute photoionization cross-section of the phenoxy radical at 118.2 nm (10.486 eV) relative to the known cross-section of the methyl radical. Even at this energy, there is extensive fragmentation of the phenoxy radical upon photoionization, which is attributed to ionizing transitions that populate low-lying excited electronic states of the cation. For phenoxy radicals with less than ∼1 eV of internal energy, we find a cross-section for the production of the phenoxy cation of 14.8 ± 3.8 Mb. For radicals with higher internal energy, dissociative ionization is the dominant process, and for internal energies of ∼2.7–3.7 eV, we find a total cross-section (photoionization plus dissociative ionization) of 22.3 ± 4.1 Mb. The results are discussed relative to the recently reported photoionization cross-section of phenol." @default.
- W2323407632 created "2016-06-24" @default.
- W2323407632 creator A5036884696 @default.
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- W2323407632 date "2013-07-25" @default.
- W2323407632 modified "2023-10-17" @default.
- W2323407632 title "Photodissociation of Anisole and Absolute Photoionization Cross-Section of the Phenoxy Radical" @default.
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- W2323407632 doi "https://doi.org/10.1021/jp4047177" @default.
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