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• W2323490652 abstract "The title compound, [Ir(η(5)-C5Me5)Cl(C18H14ClN3)]B(C6H5)4, is chiral at the metal center and crystallizes as a racemate. In the cation, the hydrazinyl-idene-pyridine ligand is N,N-coordinated through the N-pyridyl and N-hydrazinyl-idene groups forming a five-membered metallacycle. An intra-molecular C-H⋯Cl hydrogen bond is observed. In the crystal, centrosymmetrically-related cations are connected by C-Cl⋯π inter-actions, forming a dimeric structure. The crystal packing is further stabilized by weak inter-ionic C-H⋯π inter-actions." @default.
• W2323490652 created "2016-06-24" @default.
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• W2323490652 date "2015-02-18" @default.
• W2323490652 modified "2023-09-23" @default.
• W2323490652 title "Crystal structure of chlorido(2-{[2-(4-chlorophenyl)hydrazin-1-ylidene-κ<i>N</i>¹](phenyl)methyl}pyridine-κ<i>N</i>)(η⁵-pentamethylcyclopentadienyl)iridium(III) tetraphenylborate" @default.
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• W2323490652 doi "https://doi.org/10.1107/s2056989015003023" @default.
• W2323490652 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4350695" @default.
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