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- W2323504704 abstract "Small olefins from syngas The conversion of coal or natural gas to liquid fuels or chemicals often proceeds through the production of CO and H 2 . This mixture, known as syngas, is then converted to hydrocarbons with Fischer-Tropsch catalysts. For the light olefins (ethylene to butylenes) needed for chemical and polymer synthesis, conventional catalysts are mechanistically limited to <60% conversion and deactivate through carbon buildup. Jiao et al. developed a bifunctional catalyst that achieves higher conversions and avoids deactivation (see the Perspective by de Jong). A zinc-chromium oxide creates ketene intermediates that are then coupled over a zeolite. Science , this issue p. 1065 , see also p. 1030" @default.
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- W2323504704 date "2016-03-04" @default.
- W2323504704 modified "2023-10-14" @default.
- W2323504704 title "Selective conversion of syngas to light olefins" @default.
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- W2323504704 doi "https://doi.org/10.1126/science.aaf1835" @default.
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