FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2323589153> ?p ?o ?g. }

• W2323589153 abstract "Samples of three humic acids and one fulvic acid with 1% loading of benzene-d(6) in sealed glass tubes have been studied with solid-state deuterium quadrupole-echo nuclear magnetic resonance spectroscopy. Calculated spectra combining three motional models, two isotropic models and a third more restricted small-angle wobble (SAW) motional model, are fit to the experimental spectra. One isotropic motion (ISO(v)) is assigned to vaporous benzene-d(6) due to the small line width, short T(1), and the loss of this component by about -25 °C when the temperature is lowered. The remaining two motional components, ISO(s) and SAW, are sorbed by the humic or fulvic acid. Benzene-d(6) slowly interacts with the humic substances, progressively filling SAW sites as ISO(s) motion diminishes. Both the sorption and increase in percentage of SAW motion are for the most part complete within 200 days but continue to a lesser extent over a period of a few years. For the SAW motion there are at least two and most likely a series of T(1) values, indicating more than one adsorption environment. Enthalpies of sorption, obtained from application of the van't Hoff equation to the percentages of the different motional models derived from a series of variable temperature spectra, are comparable in magnitude to the enthalpy of vaporization of benzene. In Leonardite humic acid, ΔH and ΔS for the ISO(s) to SAW transition change from positive to negative values with age, implying a transition in the driving force from an entropic effect associated with expansion and deformation in the molecular structure of the humic substance to accommodate benzene-d(6) to an enthalpic effect of strong benzene-d(6)-humic substance interactions. In contrast, at advanced ages, Suwannee River humic and fulvic acids have small positive or near zero ΔH and positive ΔS for the ISO(s) to SAW transition." @default.
• W2323589153 created "2016-06-24" @default.
• W2323589153 creator A5006148678 @default.
• W2323589153 creator A5023491420 @default.
• W2323589153 creator A5066437491 @default.
• W2323589153 date "2011-04-01" @default.
• W2323589153 modified "2023-09-26" @default.
• W2323589153 title "2H NMR Study of Dynamics of Benzene-d6 Interacting with Humic and Fulvic Acids" @default.
• W2323589153 cites W1540568962 @default.
• W2323589153 cites W1971164615 @default.
• W2323589153 cites W1975212637 @default.
• W2323589153 cites W1979953245 @default.
• W2323589153 cites W1980624578 @default.
• W2323589153 cites W1981228964 @default.
• W2323589153 cites W1983552844 @default.
• W2323589153 cites W1984724158 @default.
• W2323589153 cites W1987983394 @default.
• W2323589153 cites W1990767485 @default.
• W2323589153 cites W1991429402 @default.
• W2323589153 cites W1992879948 @default.
• W2323589153 cites W1999462487 @default.
• W2323589153 cites W2001034254 @default.
• W2323589153 cites W2002406959 @default.
• W2323589153 cites W2005368762 @default.
• W2323589153 cites W2006117571 @default.
• W2323589153 cites W2008028691 @default.
• W2323589153 cites W2010089307 @default.
• W2323589153 cites W2011747626 @default.
• W2323589153 cites W2012699255 @default.
• W2323589153 cites W2015484669 @default.
• W2323589153 cites W2016069614 @default.
• W2323589153 cites W2019681083 @default.
• W2323589153 cites W2031498593 @default.
• W2323589153 cites W2037673923 @default.
• W2323589153 cites W2039221932 @default.
• W2323589153 cites W2039501616 @default.
• W2323589153 cites W2040349907 @default.
• W2323589153 cites W2041339889 @default.
• W2323589153 cites W2041675258 @default.
• W2323589153 cites W2042287869 @default.
• W2323589153 cites W2042478355 @default.
• W2323589153 cites W2046270015 @default.
• W2323589153 cites W2046811595 @default.
• W2323589153 cites W2048090917 @default.
• W2323589153 cites W2056850808 @default.
• W2323589153 cites W2065783902 @default.
• W2323589153 cites W2071712586 @default.
• W2323589153 cites W2072410969 @default.
• W2323589153 cites W2078627180 @default.
• W2323589153 cites W2080622437 @default.
• W2323589153 cites W2083267463 @default.
• W2323589153 cites W2087436284 @default.
• W2323589153 cites W2088718348 @default.
• W2323589153 cites W2094526180 @default.
• W2323589153 cites W2095495681 @default.
• W2323589153 cites W2125426196 @default.
• W2323589153 cites W2137336563 @default.
• W2323589153 cites W2522453007 @default.
• W2323589153 cites W27127529 @default.
• W2323589153 cites W4205550164 @default.
• W2323589153 cites W4234229652 @default.
• W2323589153 doi "https://doi.org/10.1021/jp111079s" @default.
• W2323589153 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21456559" @default.
• W2323589153 hasPublicationYear "2011" @default.
• W2323589153 type Work @default.
• W2323589153 sameAs 2323589153 @default.
• W2323589153 citedByCount "5" @default.
• W2323589153 countsByYear W23235891532013 @default.
• W2323589153 countsByYear W23235891532015 @default.
• W2323589153 crossrefType "journal-article" @default.
• W2323589153 hasAuthorship W2323589153A5006148678 @default.
• W2323589153 hasAuthorship W2323589153A5023491420 @default.
• W2323589153 hasAuthorship W2323589153A5066437491 @default.
• W2323589153 hasConcept C107872376 @default.
• W2323589153 hasConcept C121332964 @default.
• W2323589153 hasConcept C145912823 @default.
• W2323589153 hasConcept C147597530 @default.
• W2323589153 hasConcept C178790620 @default.
• W2323589153 hasConcept C185592680 @default.
• W2323589153 hasConcept C24890656 @default.
• W2323589153 hasConcept C2777691172 @default.
• W2323589153 hasConcept C2780151140 @default.
• W2323589153 hasConcept C2780560099 @default.
• W2323589153 hasConcept C2780965034 @default.
• W2323589153 hasConcept C59593255 @default.
• W2323589153 hasConceptScore W2323589153C107872376 @default.
• W2323589153 hasConceptScore W2323589153C121332964 @default.
• W2323589153 hasConceptScore W2323589153C145912823 @default.
• W2323589153 hasConceptScore W2323589153C147597530 @default.
• W2323589153 hasConceptScore W2323589153C178790620 @default.
• W2323589153 hasConceptScore W2323589153C185592680 @default.
• W2323589153 hasConceptScore W2323589153C24890656 @default.
• W2323589153 hasConceptScore W2323589153C2777691172 @default.
• W2323589153 hasConceptScore W2323589153C2780151140 @default.
• W2323589153 hasConceptScore W2323589153C2780560099 @default.
• W2323589153 hasConceptScore W2323589153C2780965034 @default.
• W2323589153 hasConceptScore W2323589153C59593255 @default.
• W2323589153 hasLocation W23235891531 @default.
• W2323589153 hasLocation W23235891532 @default.
• W2323589153 hasOpenAccess W2323589153 @default.

• next