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• W2323686109 abstract "Pulsed-field gradient spin–echo (PGSE) NMR is a widely used method for the determination of molecular and ionic self-diffusion coefficients. The analysis has thus far been limited largely to 1H, 7Li, 19F, and 31P nuclei. This limitation handicaps the analysis of materials without these nuclei or for which these nuclei are insufficient for complete characterization. This is demonstrated with a class of ionic liquids (or ILs) based on the nonfluorinated anion 4,5-dicarbonitrile-1,2,3-triazole (DCTA–). It is demonstrated here that 13C-PGSE NMR can be used to both verify the diffusion coefficients obtained from other nuclei, as well as characterize materials that lack commonly scrutinized nuclei — all without the need for specialized NMR methods." @default.
• W2323686109 created "2016-06-24" @default.
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• W2323686109 date "2012-01-23" @default.
• W2323686109 modified "2023-09-25" @default.
• W2323686109 title "Diffusion Coefficients from ¹³C PGSE NMR Measurements—Fluorine-Free Ionic Liquids with the DCTA^– Anion" @default.
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• W2323686109 doi "https://doi.org/10.1021/jz201700n" @default.
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