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- W2323840427 abstract "Highly luminescent ultrasmall carbon nanodots (CDs) have been prepared by one-step microwave-assisted pyrolysis and functionalized with fluorescein photosensitizer by a diazo-bond. The absorption edge of such prepared fluorescein–N═N–CDs was red-shifted in comparison with the bare one. Nevertheless, the emission signal induced by the nanoparticle quantum-sized graphite structure was quenched due to photoisomerization of the diazo group at the photoexcited state. In order to restrict the photoisomerization, i.e., rotation around the nitrogen–nitrogen bond, the diazo group was fixed by a metal cation to form a complex compound or chelate. The obtained metal complex of fluorescein–N═N–CDs shows an absorbance maximum the same as bare CDs but a recovered emission signal from the nanoparticle moiety, which was bathochromically shifted. They exhibit lower quantum yield in comparison with the bare CDs but better photostability toward emission quenching in nutrition cell culture. The formed photosensitizer-conjuga..." @default.
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- W2323840427 date "2016-04-11" @default.
- W2323840427 modified "2023-09-26" @default.
- W2323840427 title "Photosensitizer-Conjugated Ultrasmall Carbon Nanodots as Multifunctional Fluorescent Probes for Bioimaging" @default.
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- W2323840427 doi "https://doi.org/10.1021/acs.jpcc.5b11721" @default.
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