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• W2323877580 abstract "The molecular order and thermotropic transitions of tris-cis-tris-trans-dodeca- [organo(dimethylorganosiloxy)]cyclododecasiloxanes {RSi(O)[OSiMe2R′]}12 (R = Ph, R′ = Me, CH2Cl, Vi; R = Me, Et, Vi, R′ = Me) have been investigated using differential scanning calorimetry, thermogravimetric analysis, and X-ray scattering. The cyclododecasiloxanes with phenyl side groups (R = Ph) can form mesomorphic structures within a very wide temperature range. Compounds with R = Me and Vi are liquids and exhibit microphase separation above their glass transition temperature because of the different nature and structure of the organic R and trimethylsiloxy OSiMe3 side groups. When the side group R = Et, a mesomorphic structure is formed in a substantially more narrow temperature region than that for cycles containing phenyl groups. Thus, the type of side group R in organocyclododecasiloxanes determines their ability for self-ordering into mesomorphic structures and the thermal stability of the mesomorphic state." @default.
• W2323877580 created "2016-06-24" @default.
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• W2323877580 date "2011-09-12" @default.
• W2323877580 modified "2023-09-26" @default.
• W2323877580 title "Tris-<i>cis</i>-tris-<i>trans</i>-dodeca[organo(dimethylorganosiloxy)]cyclododecasiloxanes {RSi(O)[OSiMe₂R′]}₁₂. Self-Ordering Features" @default.
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• W2323877580 doi "https://doi.org/10.1021/ic2008123" @default.
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