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• W2323940841 startingPage "5561" @default.
• W2323940841 abstract "Salts containing tetraaryldiphosphine radical cation 1(•+) and dication 1(2+) have been isolated and structurally characterized. Radical 1(•+) has a relaxed pyramidal geometry, while dication 1(2+) prefers a planar, olefin-like geometry with a two-electron π bond. The alteration of the geometries of the tetraaryldiphosphine upon oxidation is rationalized by the nature of the bonding. The EPR spectrum showed that the spin density of radical 1(•+) is mainly localized on phosphorus atoms, which is supported by theoretical calculation." @default.
• W2323940841 created "2016-06-24" @default.
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• W2323940841 date "2013-04-05" @default.
• W2323940841 modified "2023-09-30" @default.
• W2323940841 title "Stable Tetraaryldiphosphine Radical Cation and Dication" @default.
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• W2323940841 doi "https://doi.org/10.1021/ja402492u" @default.
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