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• W2323962682 endingPage "6684" @default.
• W2323962682 startingPage "6681" @default.
• W2323962682 abstract "The first entry to statins via lactonized side chain is reported, exemplified by the synthesis of rosuvastatin. The key step is Wittig coupling of (2S,4R)-4-(tert-butyldimethylsilyloxy)-6-oxotetrahydro-2H-pyran-2-carbaldehyde and phosphonium salt of an appropriately functionalized pyrimidine heterocycle. One-pot deprotection and hydrolysis of the resulting 4-O-TBS rosuvastatin lactone provided rosuvastatin in high yield." @default.
• W2323962682 created "2016-06-24" @default.
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• W2323962682 date "2010-09-03" @default.
• W2323962682 modified "2023-10-06" @default.
• W2323962682 title "Lactone Pathway to Statins Utilizing the Wittig Reaction. The Synthesis of Rosuvastatin" @default.
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• W2323962682 doi "https://doi.org/10.1021/jo101050z" @default.
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