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• W2324100400 endingPage "1250" @default.
• W2324100400 startingPage "1239" @default.
• W2324100400 abstract "The yttrium carbene complex [Y(BIPM)(I)(THF)2] (1; BIPM = C(PPh2NSiMe3)2) was reacted with a range of unsaturated substrates. The reaction of 1 with the phosphaalkyne PCBut afforded the [2 + 2] cycloaddition product [Y{C(PPh2NSiMe3)2(PCBut)-κ4C,C′,N,N′}(I)] (2). Similarly, the reactions of 1 with the heteroallenes N,N′-dicyclohexylcarbodiimide and tert-butyl isocyanate gave the [2 + 2] cycloaddition products [Y{C(PPh2NSiMe3)2[C(NCy)2]-κ4C,N,N′,N″}(I)(THF)] (3) and [Y{C(PPh2NSiMe3)2[C(O)(NBut)]-κ4C,N,N′,O}(I)(THF)2] (4), respectively. In contrast, the reaction of 1 with tert-butyl isothiocyanate afforded the ketenimine ButN═C═C(PPh2NSiMe3)2 (5), with the concomitant formal elimination of “YSI(THF)n”. The sterically demanding arylamine 2,6-diisopropylphenylamine reacted with 1 via a 1,2-addition across the Y═C bond to yield the anilide–methanide complex [Y(BIPMH)(NHDipp)(I)(THF)] (6; Dipp = C6H3Pri2-2,6). The reaction of 1 with the benzopyrone coumarin affords the ring-opened dinuclear aryloxide–enolate complex [Y2{C(PPh2NSiMe3)2[C(O)(CHCHC6H4O-2)]-κ2-N,O:μ,κ-O′}2(I)(μ-I)(THF)] (7), which is postulated to form by sequential Y–O, C–C, and C═C bond formation and cleavage of the C–O ester linkage and the C═O and Y═C double bonds. Benzoyl fluoride reacts with 1 to afford 1/2 equiv of the bis-enolate complex [Y{C(PPh2NSiMe3)2[C(O)(Ph)]-κ2N,O}2(I)] (8) with formal elimination of “YF2I(THF)n” by ligand scrambling. Complexes 2–8 have been characterized by X-ray crystallography, multielement NMR spectroscopy, FTIR spectroscopy, and CHN microanalyses." @default.
• W2324100400 created "2016-06-24" @default.
• W2324100400 creator A5015509328 @default.
• W2324100400 creator A5039618848 @default.
• W2324100400 creator A5084750854 @default.
• W2324100400 creator A5086963679 @default.
• W2324100400 date "2013-02-12" @default.
• W2324100400 modified "2023-10-10" @default.
• W2324100400 title "Reactivity Studies of a T-Shaped Yttrium Carbene: C–F and C–O Bond Activation and C═C Bond Formation Promoted by [Y(BIPM)(I)(THF)₂] (BIPM = C(PPh₂NSiMe₃)₂)" @default.
• W2324100400 cites W1833136511 @default.
• W2324100400 cites W1968414994 @default.
• W2324100400 cites W1968782996 @default.
• W2324100400 cites W1970683734 @default.
• W2324100400 cites W1972514222 @default.
• W2324100400 cites W1973360498 @default.
• W2324100400 cites W1974711265 @default.
• W2324100400 cites W1975898567 @default.
• W2324100400 cites W1986137087 @default.
• W2324100400 cites W1988567165 @default.
• W2324100400 cites W1988920922 @default.
• W2324100400 cites W1994890915 @default.
• W2324100400 cites W1998077264 @default.
• W2324100400 cites W1998200350 @default.
• W2324100400 cites W2000362621 @default.
• W2324100400 cites W2007302041 @default.
• W2324100400 cites W2009619698 @default.
• W2324100400 cites W2013117933 @default.
• W2324100400 cites W2013600799 @default.
• W2324100400 cites W2016304228 @default.
• W2324100400 cites W2019176142 @default.
• W2324100400 cites W2019913856 @default.
• W2324100400 cites W2022144021 @default.
• W2324100400 cites W2023896599 @default.
• W2324100400 cites W2024863575 @default.
• W2324100400 cites W2025593360 @default.
• W2324100400 cites W2028194121 @default.
• W2324100400 cites W2030340979 @default.
• W2324100400 cites W2031829063 @default.
• W2324100400 cites W2032842297 @default.
• W2324100400 cites W2040424369 @default.
• W2324100400 cites W2042483575 @default.
• W2324100400 cites W2043919887 @default.
• W2324100400 cites W2045031649 @default.
• W2324100400 cites W2045952062 @default.
• W2324100400 cites W2046305422 @default.
• W2324100400 cites W2046924926 @default.
• W2324100400 cites W2048082206 @default.
• W2324100400 cites W2050543923 @default.
• W2324100400 cites W2051463644 @default.
• W2324100400 cites W2052691188 @default.
• W2324100400 cites W2055248277 @default.
• W2324100400 cites W2057732674 @default.
• W2324100400 cites W2059205366 @default.
• W2324100400 cites W2062940198 @default.
• W2324100400 cites W2064978746 @default.
• W2324100400 cites W2065169748 @default.
• W2324100400 cites W2067451258 @default.
• W2324100400 cites W2074574430 @default.
• W2324100400 cites W2075020241 @default.
• W2324100400 cites W2077868644 @default.
• W2324100400 cites W2078435968 @default.
• W2324100400 cites W2083799106 @default.
• W2324100400 cites W2084629763 @default.
• W2324100400 cites W2085615658 @default.
• W2324100400 cites W2089028348 @default.
• W2324100400 cites W2089412884 @default.
• W2324100400 cites W2092999099 @default.
• W2324100400 cites W2093915799 @default.
• W2324100400 cites W2112304442 @default.
• W2324100400 cites W2118126257 @default.
• W2324100400 cites W2120395928 @default.
• W2324100400 cites W2131350133 @default.
• W2324100400 cites W2137013960 @default.
• W2324100400 cites W2158392096 @default.
• W2324100400 cites W2158621087 @default.
• W2324100400 cites W2160923526 @default.
• W2324100400 cites W2168542043 @default.
• W2324100400 cites W2169136539 @default.
• W2324100400 cites W2170365874 @default.
• W2324100400 cites W2314129795 @default.
• W2324100400 cites W2334869778 @default.
• W2324100400 cites W2949386214 @default.
• W2324100400 cites W2953005242 @default.
• W2324100400 doi "https://doi.org/10.1021/om301016j" @default.
• W2324100400 hasPublicationYear "2013" @default.
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