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- W2324110249 abstract "The structure of doubly ionized benzene has been spectroscopically studied for the first time. Helium-tagged complexes were prepared at temperatures below 4 K and analyzed using infrared predissociation spectroscopy. Double ionization of benzene yields primarily high-energy dications with a six-membered-ring structure. Some of the dications undergo rearrangement to a more stable pyramidal isomer with a C5H5 base and CH at the apex. By means of isomer-selective heating by a CO2 laser, infrared predissociation spectra of both the classical and pyramidal dications were obtained." @default.
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- W2324110249 date "2014-02-18" @default.
- W2324110249 modified "2023-10-18" @default.
- W2324110249 title "Probing Isomers of the Benzene Dication in a Low-Temperature Trap" @default.
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- W2324110249 doi "https://doi.org/10.1021/ja412109h" @default.
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