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• W2324116096 abstract "The photoelectron images of Ag–(H2O)x (x = 1,2) and AgOH–(H2O)y (y = 0–4) are reported. The Ag–(H2O)1,2 anionic complexes have similar characteristics to the other two coinage metal–water complexes that can be characterized as metal atomic anion solvated by water molecules with the electron mainly localized on the metal. The vibrationally well-resolved photoelectron spectrum allows the adiabatic detachment energy (ADE) and vertical detachment energy (VDE) of AgOH– to be determined as 1.18(2) and 1.24(2) eV, respectively. The AgOH– anion interacts more strongly with water molecules than the Ag– anion. The photoelectron spectra of Ag–(H2O)x and AgOH–(H2O)y show a gradual increase in ADE and VDE with increasing x and y due to the solvent stabilization." @default.
• W2324116096 created "2016-06-24" @default.
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• W2324116096 date "2011-05-09" @default.
• W2324116096 modified "2023-09-24" @default.
• W2324116096 title "Photoelectron Imaging of Ag^–(H₂O)_<i>x</i> and AgOH^–(H₂O)_<i>y</i> (<i>x</i> = 1,2, <i>y</i> = 0–4)" @default.
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• W2324116096 doi "https://doi.org/10.1021/jp202497x" @default.
• W2324116096 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21553859" @default.
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