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- W2324135585 abstract "フェロマンガンおよびマンガンスラッグ中のマンガンをKolthoffらの提案しているピロ燐酸支持塩を用いてポーラログラフ分析を試みた結果つぎのことがわかった.(1)0.3Mピロ燐酸塩中のポーラログラフ波はpHが2.5～3.4の範囲内では一定値を示し,マンガン(III)→(II)の比較的よい還元波を示す.(2)極大抑制剤としてゼラチンの0.01%濃度を使用した場合50mg/100ml位までのマンガン量は良好な比例性が成立するが,それ以上になると極大も現れ比例性も悪くなる.(3)ピロ燐酸塩中でのマンガン(III)波は+0.15Vvs.S.C.E.ですでに限界電流に達するので,大過剰の鉄,およびクロム,バナジウム,塩素の他は妨害とならない.(4)実際の試料について蒼鉛酸ソーダ法と比較分析したところ,精度もよく,迅速に分析することができた." @default.
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- W2324135585 date "1958-01-01" @default.
- W2324135585 modified "2023-09-24" @default.
- W2324135585 title "Rapid polarographic determination of manganese in ferromanganese and manganese slag" @default.
- W2324135585 doi "https://doi.org/10.2116/bunsekikagaku.7.25" @default.
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