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- W2324136175 abstract "Abstract Available kinetic data on aromatic sulfonation with SO3 are critically reviewed. It is concluded that the kinetic reaction rate of the sulfonation of benzene with sulphur trioxide at 25°C is fast compared to the rate of the mass transfer process, moreover it is concluded that the value of the mass transfer coefficient realized in a particular reactor may influence the selectivity of the sulfonation reaction. Experimental results on sulfonation of 30 vol% benzene in 1,2 dichloroethane using three types of gas-liquid reactors which greatly differ in mass transfer characteristics have been summarized. The results show a decrease of the formation of the by-product diphenyl sulfone with increasing liquid side mass transfer coefficient. Especially in a cyclone reactor, by-product formation could be considerably suppressed. Based on the kinetic picture derived, the relationship between sulfone formation and mass transfer coefficient is qualitatively understood." @default.
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- W2324136175 date "1981-06-01" @default.
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- W2324136175 title "KINETICS AND INFLUENCE OF MASS TRANSFER ON SELECTIVITY IN THE SULFONATION OF BENZENE WITH SULFUR TRIOXIDE" @default.
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- W2324136175 doi "https://doi.org/10.1080/03086648108077509" @default.
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