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- W2324141808 abstract "Visible light driven catalysis on metal surfaces and nanoparticles has attracted significant attention in recent years as a potential route for driving selective chemical reactions that are difficult to achieve with thermal energy. It is most often assumed that photochemistry on metal surfaces occurs through a substrate-mediated process of adsorbate-metal bond photoexcitation, although crucial underlying phenomena controlling the efficiency of this process are still poorly understood. In this work, substrate-mediated photochemistry on metal surfaces was analyzed by combining dynamical models associated with the metal substrate photoexcitation and electron-mediated bond-activation processes. An extended version of two-temperature model was utilized to treat temporal evolution of photoexcited charge carriers in the metal substrate. The electron-induced adsorbate dynamics on the metal surface was modeled using a nonadiabatic, first-principles based inelastic electron scattering model. Photoactivation of three well studied reactions on Pt(111) surfaces, CO and NO desorption and O diffusion, were chosen as model systems. Through our approach, we addressed unresolved issues associated with adsorbate specific reaction time scales and wavelength and temperature-dependent behavior. The results suggest that activating adsorbate-metal bonds with targeted photon wavelengths and at optimal system temperatures could provide an approach to control selectivity in photon-driven reactions on metal surfaces." @default.
- W2324141808 created "2016-06-24" @default.
- W2324141808 creator A5047217534 @default.
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- W2324141808 date "2014-11-20" @default.
- W2324141808 modified "2023-10-16" @default.
- W2324141808 title "Adsorbate Specificity in Hot Electron Driven Photochemistry on Catalytic Metal Surfaces" @default.
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- W2324141808 doi "https://doi.org/10.1021/jp509555m" @default.
- W2324141808 hasPublicationYear "2014" @default.
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