FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2324155307> ?p ?o ?g. }

• W2324155307 endingPage "18549" @default.
• W2324155307 startingPage "18546" @default.
• W2324155307 abstract "Ferric tetraamido macrocyclic ligand (TAML)-based catalysts [Fe{C6H4-1,2-(NCOCMe2NCO)2CR2}(OH2)]PPh4 [1; R = Me (a), Et (b)] are oxidized by m-chloroperoxybenzoic acid at −40 °C in acetonitrile containing trace water in two steps to form Fe(V)oxo complexes (2a,b). These uniquely authenticated FeV(O) species comproportionate with the FeIII starting materials 1a,b to give μ-oxo-(FeIV)2 dimers. The comproportionation of 1a–2a is faster and that of 1b–2b is slower than the oxidation by 2a,b of sulfides (p-XC6H4SMe) to sulfoxides, highlighting a remarkable steric control of the dynamics. Sulfide oxidation follows saturation kinetics in [p-XC6H4SMe] with electron-rich substrates (X = Me, H), but changes to linear kinetics with electron-poor substrates (X = Cl, CN) as the sulfide affinity for iron decreases. As the sulfide becomes less basic, the FeIV/FeIII ratio at the end of reaction for 2b suggests a decreasing contribution of concerted oxygen-atom transfer (FeV → FeIII) concomitant with increasing electron transfer oxidation (FeV → FeIV). FeV is more reactive toward PhSMe than FeIV by 4 orders of magnitude, a gap even larger than that known for peroxidase Compounds I and II. The findings reinforce prior work typecasting TAML activators as faithful peroxidase mimics." @default.
• W2324155307 created "2016-06-24" @default.
• W2324155307 creator A5048108236 @default.
• W2324155307 creator A5049632677 @default.
• W2324155307 creator A5087798538 @default.
• W2324155307 creator A5091649631 @default.
• W2324155307 date "2011-10-27" @default.
• W2324155307 modified "2023-10-16" @default.
• W2324155307 title "On the Reactivity of Mononuclear Iron(V)oxo Complexes" @default.
• W2324155307 cites W1967700647 @default.
• W2324155307 cites W1970522028 @default.
• W2324155307 cites W1976670245 @default.
• W2324155307 cites W1984449938 @default.
• W2324155307 cites W1986260849 @default.
• W2324155307 cites W1986513799 @default.
• W2324155307 cites W1997952970 @default.
• W2324155307 cites W2001480824 @default.
• W2324155307 cites W2003688694 @default.
• W2324155307 cites W2007724872 @default.
• W2324155307 cites W2024195093 @default.
• W2324155307 cites W2056064842 @default.
• W2324155307 cites W2069299962 @default.
• W2324155307 cites W2072648963 @default.
• W2324155307 cites W2078567919 @default.
• W2324155307 cites W2084902151 @default.
• W2324155307 cites W2087593458 @default.
• W2324155307 cites W2095279996 @default.
• W2324155307 cites W2105200096 @default.
• W2324155307 cites W2138069732 @default.
• W2324155307 cites W2144834490 @default.
• W2324155307 cites W2159427603 @default.
• W2324155307 cites W2160790360 @default.
• W2324155307 cites W2312726166 @default.
• W2324155307 cites W2325842257 @default.
• W2324155307 cites W2489432010 @default.
• W2324155307 cites W271395101 @default.
• W2324155307 doi "https://doi.org/10.1021/ja208007w" @default.
• W2324155307 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21985217" @default.
• W2324155307 hasPublicationYear "2011" @default.
• W2324155307 type Work @default.
• W2324155307 sameAs 2324155307 @default.
• W2324155307 citedByCount "69" @default.
• W2324155307 countsByYear W23241553072012 @default.
• W2324155307 countsByYear W23241553072013 @default.
• W2324155307 countsByYear W23241553072014 @default.
• W2324155307 countsByYear W23241553072015 @default.
• W2324155307 countsByYear W23241553072016 @default.
• W2324155307 countsByYear W23241553072017 @default.
• W2324155307 countsByYear W23241553072018 @default.
• W2324155307 countsByYear W23241553072019 @default.
• W2324155307 countsByYear W23241553072020 @default.
• W2324155307 countsByYear W23241553072021 @default.
• W2324155307 countsByYear W23241553072022 @default.
• W2324155307 crossrefType "journal-article" @default.
• W2324155307 hasAuthorship W2324155307A5048108236 @default.
• W2324155307 hasAuthorship W2324155307A5049632677 @default.
• W2324155307 hasAuthorship W2324155307A5087798538 @default.
• W2324155307 hasAuthorship W2324155307A5091649631 @default.
• W2324155307 hasConcept C116569031 @default.
• W2324155307 hasConcept C121332964 @default.
• W2324155307 hasConcept C123669783 @default.
• W2324155307 hasConcept C142724271 @default.
• W2324155307 hasConcept C147789679 @default.
• W2324155307 hasConcept C148898269 @default.
• W2324155307 hasConcept C155647269 @default.
• W2324155307 hasConcept C164397293 @default.
• W2324155307 hasConcept C170493617 @default.
• W2324155307 hasConcept C17525397 @default.
• W2324155307 hasConcept C178790620 @default.
• W2324155307 hasConcept C179104552 @default.
• W2324155307 hasConcept C185592680 @default.
• W2324155307 hasConcept C201194858 @default.
• W2324155307 hasConcept C204787440 @default.
• W2324155307 hasConcept C2776910235 @default.
• W2324155307 hasConcept C2777463227 @default.
• W2324155307 hasConcept C2780534640 @default.
• W2324155307 hasConcept C2780596425 @default.
• W2324155307 hasConcept C52859227 @default.
• W2324155307 hasConcept C55493867 @default.
• W2324155307 hasConcept C62520636 @default.
• W2324155307 hasConcept C71240020 @default.
• W2324155307 hasConcept C71924100 @default.
• W2324155307 hasConcept C75473681 @default.
• W2324155307 hasConceptScore W2324155307C116569031 @default.
• W2324155307 hasConceptScore W2324155307C121332964 @default.
• W2324155307 hasConceptScore W2324155307C123669783 @default.
• W2324155307 hasConceptScore W2324155307C142724271 @default.
• W2324155307 hasConceptScore W2324155307C147789679 @default.
• W2324155307 hasConceptScore W2324155307C148898269 @default.
• W2324155307 hasConceptScore W2324155307C155647269 @default.
• W2324155307 hasConceptScore W2324155307C164397293 @default.
• W2324155307 hasConceptScore W2324155307C170493617 @default.
• W2324155307 hasConceptScore W2324155307C17525397 @default.
• W2324155307 hasConceptScore W2324155307C178790620 @default.
• W2324155307 hasConceptScore W2324155307C179104552 @default.
• W2324155307 hasConceptScore W2324155307C185592680 @default.
• W2324155307 hasConceptScore W2324155307C201194858 @default.
• W2324155307 hasConceptScore W2324155307C204787440 @default.

• next