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- W2324177776 abstract "MOLECULAR MANUFACTURING'S ultimate goal of assembling molecular machines atom by atom may be a long way off, but a research team in Europe has come a step closer to assembling structures molecule by molecule. In an elegant meeting of chemistry and mechanics at the single-molecule level, Anne-Sophie Duwez, a materials scientist at Belgium's University of Liege, and colleagues use an atomic force microscope (AFM) to covalently attach individual molecules to a surface, making and breaking each bond individually ( Nat. Nanotechnol ., DOI: 10.1038/nnano.2006.92). The ultimate physical limit in the design and fabrication of organic surfaces can be reached using this approach, according to Duwez. To achieve their mechanosynthesis, Duwez' group grafts poly- N -succinimidyl acrylate onto a gold-coated AFM tip. They then carefully bring this modified AFM tip into contact with a silicon surface functionalized with primary amines. A nucleophilic amine attacks a reactive carbonyl on the polymer, forming an amide lin..." @default.
- W2324177776 created "2016-06-24" @default.
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- W2324177776 date "2006-11-06" @default.
- W2324177776 modified "2023-09-24" @default.
- W2324177776 title "STEP-BY-STEP SURFACE ASSEMBLY" @default.
- W2324177776 doi "https://doi.org/10.1021/cen-v084n045.p010a" @default.
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