FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2324203624> ?p ?o ?g. }

• W2324203624 endingPage "13301" @default.
• W2324203624 startingPage "13298" @default.
• W2324203624 abstract "A binuclear metal coordination complex of the first thiazyl-based biradical ligand 1 is reported (1 = 4,6-bis(1,2,3,5-dithiadiazolyl)pyrimidine; hfac =1,1,1,5,5,5,-hexafluoroacetylacetonato-). The Mn(hfac)2-biradical-Mn(hfac)2 complex 2 is a rare example of a discrete, molecular species employing a neutral bridging biradical ligand. It is soluble in common organic solvents and can be easily sublimed as a crystalline solid. Complex 2 has a spin ground state of ST = 4 resulting from antiferromagnetic coupling between the Sbirad = 1 biradical bridging ligand and two SMn = 5/2 MnII ions. Electrostatic contacts between atoms with large spin density promote a ferromagnetic arrangement of the moments of neighboring complexes in ribbon-like arrays. Weak antiferromagnetic coupling between these high-spin ribbons stabilizes an ordered antiferromagnetic ground state below 4.5 K. This is an unusual example of magnetic ordering in a molecular metal-radical complex, wherein the electrostatic contacts that direct the crystal packing are also responsible for providing an efficient exchange coupling pathway between molecules." @default.
• W2324203624 created "2016-06-24" @default.
• W2324203624 creator A5006104613 @default.
• W2324203624 creator A5012804768 @default.
• W2324203624 creator A5031459453 @default.
• W2324203624 creator A5052194742 @default.
• W2324203624 creator A5059803666 @default.
• W2324203624 creator A5070668695 @default.
• W2324203624 date "2013-08-30" @default.
• W2324203624 modified "2023-09-25" @default.
• W2324203624 title "High-Spin Ribbons and Antiferromagnetic Ordering of a Mn^II-Biradical-Mn^II Complex" @default.
• W2324203624 cites W1565595557 @default.
• W2324203624 cites W1963819553 @default.
• W2324203624 cites W1966017419 @default.
• W2324203624 cites W1966078306 @default.
• W2324203624 cites W1976626282 @default.
• W2324203624 cites W1977953300 @default.
• W2324203624 cites W1982718611 @default.
• W2324203624 cites W1998586509 @default.
• W2324203624 cites W1999213367 @default.
• W2324203624 cites W1999598381 @default.
• W2324203624 cites W1999824247 @default.
• W2324203624 cites W2001366215 @default.
• W2324203624 cites W2009482366 @default.
• W2324203624 cites W2013930884 @default.
• W2324203624 cites W2018847427 @default.
• W2324203624 cites W2022327079 @default.
• W2324203624 cites W2024278928 @default.
• W2324203624 cites W2029533367 @default.
• W2324203624 cites W2045217272 @default.
• W2324203624 cites W2054142759 @default.
• W2324203624 cites W2067710734 @default.
• W2324203624 cites W2076626161 @default.
• W2324203624 cites W2086090314 @default.
• W2324203624 cites W2090777387 @default.
• W2324203624 cites W2093963466 @default.
• W2324203624 cites W2095392154 @default.
• W2324203624 cites W2095399338 @default.
• W2324203624 cites W2148181964 @default.
• W2324203624 cites W2150495750 @default.
• W2324203624 cites W2165455378 @default.
• W2324203624 cites W2312573082 @default.
• W2324203624 cites W2320128901 @default.
• W2324203624 cites W2323682803 @default.
• W2324203624 cites W2332916197 @default.
• W2324203624 cites W3149694049 @default.
• W2324203624 cites W319120409 @default.
• W2324203624 cites W4231215563 @default.
• W2324203624 cites W4251644397 @default.
• W2324203624 doi "https://doi.org/10.1021/ja4067783" @default.
• W2324203624 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23984987" @default.
• W2324203624 hasPublicationYear "2013" @default.
• W2324203624 type Work @default.
• W2324203624 sameAs 2324203624 @default.
• W2324203624 citedByCount "25" @default.
• W2324203624 countsByYear W23242036242013 @default.
• W2324203624 countsByYear W23242036242014 @default.
• W2324203624 countsByYear W23242036242015 @default.
• W2324203624 countsByYear W23242036242016 @default.
• W2324203624 countsByYear W23242036242017 @default.
• W2324203624 countsByYear W23242036242018 @default.
• W2324203624 countsByYear W23242036242019 @default.
• W2324203624 countsByYear W23242036242020 @default.
• W2324203624 countsByYear W23242036242021 @default.
• W2324203624 countsByYear W23242036242022 @default.
• W2324203624 crossrefType "journal-article" @default.
• W2324203624 hasAuthorship W2324203624A5006104613 @default.
• W2324203624 hasAuthorship W2324203624A5012804768 @default.
• W2324203624 hasAuthorship W2324203624A5031459453 @default.
• W2324203624 hasAuthorship W2324203624A5052194742 @default.
• W2324203624 hasAuthorship W2324203624A5059803666 @default.
• W2324203624 hasAuthorship W2324203624A5070668695 @default.
• W2324203624 hasConcept C115624301 @default.
• W2324203624 hasConcept C116569031 @default.
• W2324203624 hasConcept C121332964 @default.
• W2324203624 hasConcept C155355069 @default.
• W2324203624 hasConcept C170493617 @default.
• W2324203624 hasConcept C178790620 @default.
• W2324203624 hasConcept C184779094 @default.
• W2324203624 hasConcept C185592680 @default.
• W2324203624 hasConcept C26873012 @default.
• W2324203624 hasConcept C32909587 @default.
• W2324203624 hasConcept C544153396 @default.
• W2324203624 hasConcept C55352516 @default.
• W2324203624 hasConcept C55493867 @default.
• W2324203624 hasConcept C69523127 @default.
• W2324203624 hasConcept C8010536 @default.
• W2324203624 hasConcept C82217956 @default.
• W2324203624 hasConceptScore W2324203624C115624301 @default.
• W2324203624 hasConceptScore W2324203624C116569031 @default.
• W2324203624 hasConceptScore W2324203624C121332964 @default.
• W2324203624 hasConceptScore W2324203624C155355069 @default.
• W2324203624 hasConceptScore W2324203624C170493617 @default.
• W2324203624 hasConceptScore W2324203624C178790620 @default.
• W2324203624 hasConceptScore W2324203624C184779094 @default.
• W2324203624 hasConceptScore W2324203624C185592680 @default.
• W2324203624 hasConceptScore W2324203624C26873012 @default.
• W2324203624 hasConceptScore W2324203624C32909587 @default.

• next