Matches in SemOpenAlex for { <https://semopenalex.org/work/W2324227968> ?p ?o ?g. }
- W2324227968 endingPage "5312" @default.
- W2324227968 startingPage "5305" @default.
- W2324227968 abstract "Nitrogen-rich 5-(1-methylhydrazinyl)tetrazole (1, MHT) was synthesized by using a straightforward method. White plate crystals of 1 were isolated in acetonitrile and crystallized in the monoclinic system P21/c (# 14) (a = 3.8713(18) Å, b = 12.770(6) Å, c = 9.974(5) Å, α = 90°, β = 93.397(6)°, γ = 90°, V = 492.3(4) Å3, Z = 4). The reactions of Cu(II) and Ag(I) ions in aqueous solution with 1 were investigated and found to form two complexes under mild conditions. The crystal structures of 2 and 3 are discussed with respect to the coordination mode of the MHT anion. Thermal stabilities were determined from differential scanning calorimetry (DSC) combined with thermogravimetric analysis (TGA) tests. Impact sensitivity was determined by BAM standards showing that these MHT salts are insensitive to impact (>40 J) confirmed by UN standards. The energies of combustion of 1–3 were determined using oxygen bomb calorimetry values and were used to obtain the corresponding enthalpies of formation. Combined with these data above, the neutral MHT is an attractive nitrogen-rich ligand for metallic energetic materials. Its copper and silver coordinated complexes are of interest as potential “green” metal energetic materials with high thermal stability as well as low sensitivity to impact and a high molar enthalpy of formation." @default.
- W2324227968 created "2016-06-24" @default.
- W2324227968 creator A5004938908 @default.
- W2324227968 creator A5006127080 @default.
- W2324227968 creator A5052221803 @default.
- W2324227968 date "2012-04-09" @default.
- W2324227968 modified "2023-10-14" @default.
- W2324227968 title "Nitrogen-Rich 5-(1-Methylhydrazinyl)tetrazole and its Copper and Silver Complexes" @default.
- W2324227968 cites W1964424589 @default.
- W2324227968 cites W1966385423 @default.
- W2324227968 cites W1972711445 @default.
- W2324227968 cites W1982134120 @default.
- W2324227968 cites W1984945175 @default.
- W2324227968 cites W2000901547 @default.
- W2324227968 cites W2003815793 @default.
- W2324227968 cites W2010994682 @default.
- W2324227968 cites W2011448330 @default.
- W2324227968 cites W2011602559 @default.
- W2324227968 cites W2012187236 @default.
- W2324227968 cites W2017269103 @default.
- W2324227968 cites W2030141832 @default.
- W2324227968 cites W2032444609 @default.
- W2324227968 cites W2038232512 @default.
- W2324227968 cites W2042465985 @default.
- W2324227968 cites W2042899352 @default.
- W2324227968 cites W2044559893 @default.
- W2324227968 cites W2046078734 @default.
- W2324227968 cites W2051069449 @default.
- W2324227968 cites W2055725780 @default.
- W2324227968 cites W2060456751 @default.
- W2324227968 cites W2069127738 @default.
- W2324227968 cites W2078135278 @default.
- W2324227968 cites W2078376925 @default.
- W2324227968 cites W2080683406 @default.
- W2324227968 cites W2081526896 @default.
- W2324227968 cites W2082498545 @default.
- W2324227968 cites W2083560373 @default.
- W2324227968 cites W2085019034 @default.
- W2324227968 cites W2086526979 @default.
- W2324227968 cites W2087425616 @default.
- W2324227968 cites W2091730472 @default.
- W2324227968 cites W2095572837 @default.
- W2324227968 cites W2106982586 @default.
- W2324227968 cites W2113338846 @default.
- W2324227968 cites W2126953413 @default.
- W2324227968 cites W2128473478 @default.
- W2324227968 cites W2128765349 @default.
- W2324227968 cites W2135779111 @default.
- W2324227968 cites W2147566688 @default.
- W2324227968 cites W2150451038 @default.
- W2324227968 cites W2151067707 @default.
- W2324227968 cites W2152444872 @default.
- W2324227968 cites W2163548088 @default.
- W2324227968 cites W2166206102 @default.
- W2324227968 cites W2291438781 @default.
- W2324227968 cites W2319712954 @default.
- W2324227968 cites W2335692242 @default.
- W2324227968 cites W2951425625 @default.
- W2324227968 cites W3026687412 @default.
- W2324227968 cites W4238022666 @default.
- W2324227968 cites W4238904229 @default.
- W2324227968 cites W4254932031 @default.
- W2324227968 cites W576075765 @default.
- W2324227968 doi "https://doi.org/10.1021/ic300242e" @default.
- W2324227968 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22486392" @default.
- W2324227968 hasPublicationYear "2012" @default.
- W2324227968 type Work @default.
- W2324227968 sameAs 2324227968 @default.
- W2324227968 citedByCount "73" @default.
- W2324227968 countsByYear W23242279682012 @default.
- W2324227968 countsByYear W23242279682013 @default.
- W2324227968 countsByYear W23242279682014 @default.
- W2324227968 countsByYear W23242279682015 @default.
- W2324227968 countsByYear W23242279682016 @default.
- W2324227968 countsByYear W23242279682017 @default.
- W2324227968 countsByYear W23242279682018 @default.
- W2324227968 countsByYear W23242279682019 @default.
- W2324227968 countsByYear W23242279682020 @default.
- W2324227968 countsByYear W23242279682021 @default.
- W2324227968 countsByYear W23242279682022 @default.
- W2324227968 countsByYear W23242279682023 @default.
- W2324227968 crossrefType "journal-article" @default.
- W2324227968 hasAuthorship W2324227968A5004938908 @default.
- W2324227968 hasAuthorship W2324227968A5006127080 @default.
- W2324227968 hasAuthorship W2324227968A5052221803 @default.
- W2324227968 hasConcept C115624301 @default.
- W2324227968 hasConcept C121332964 @default.
- W2324227968 hasConcept C147368240 @default.
- W2324227968 hasConcept C147789679 @default.
- W2324227968 hasConcept C178790620 @default.
- W2324227968 hasConcept C179104552 @default.
- W2324227968 hasConcept C184651966 @default.
- W2324227968 hasConcept C185592680 @default.
- W2324227968 hasConcept C199164860 @default.
- W2324227968 hasConcept C202270520 @default.
- W2324227968 hasConcept C2777463227 @default.
- W2324227968 hasConcept C2780827033 @default.
- W2324227968 hasConcept C3288061 @default.